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In this paper, the nanocrystalling composite Mg-Ni-TiO2-CNTs was made by mechanical ball milling under hydrogen pressure of 5.0×10-5Pa, The hydrogen storage properties and operation temperatures were investigated. It was found that the composite can absorb 7.5wt.% hydrogen in 60s under 5.0×10-5Pa hydrogen pressure and desorb 6.5wt% hydrogen in 600s at 260°C under 5.0×10-5Pa hydrogen pressure. The composite has very high absorption, hydrogen capacity and remarkable kinetic properties in hydriding /dehydeiding process. TiO2, Ni and CNTs were used as additive to improve the hydrogen storage performance. They can be utilized as an effective catalyst to improve hydriding/dehydriding performance of hydrogen storage material and lead to pronounced enhancement on the hydrogen storage property of Mg. The results showed that the composite has potential application in the future.
Here we used the iron oxide nanoparticles derived from ferritin as catalyst for the synthesis of carbon nanotubes (CNTs) by the chemical vapor deposition (CVD) of coal gas. It has been found that the structure and morphology of CNTs can be tailored, to some degree, by varying the experimental conditions such as catalyst loading and process parameters. In addition to straight CNTs, some Y-branched CNTs were also obtained, which might be due to the sulfur species in the coal gas.