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Bi(1.98-x)In0.02NaxTe2.7Se0.3 (x = 0, 0.02, 0.04, 0.06) and Bi2Te2.7Se0.3 alloys were prepared by vacuum melting and hot pressing methods. The phase structure of the bulk samples were characterized by X-ray diffraction. Effects of indium and sodium co-substitutions for bismuth on the electrical and thermal transport properties were investigated in the temperature range of 298–473 K. Indium and sodium co-doping can enhance the carrier concentration, and accordingly the electrical conductivity can be improved effectively. The Seebeck coefficients of the co-doped samples have not been derogated strongly. The power factors are enhanced for the Bi(1.98-x)In0.02NaxTe2.7Se0.3 (x = 0.02) within the whole testing temperature range. The Bi(1.98-x)In0.02NaxTe2.7Se0.3 (x = 0.02) samples have the lower thermal conductivity due to reduction in lattice thermal conductivity, which leads to a great improvement in the thermoelectric figure of merit ZT. The highest ZT of the sample can reach 0.87 at 398 K.
Translucent alumina doped with ZrO2 and MgO was fabricated by two-step vacuum sintering (1475∘C/30min followed by 1320∘C/20min) with a high heating rate (80∘C/min). Densification, grain size, phase composition, mechanical properties and translucency of the alumina were investigated. The results indicated that co-doping of ZrO2 and MgO showed a synergetic effect on grain refinement and densification process. On one hand, the solubility of MgO in alumina was increased by the ZrO2 additive, which was favorable for the densification. On the other hand, more favorable ZrO2 accommodation sites existed at the alumina grain boundaries created by the MgO, effectively decreasing the grain size. Finally, the sample with porosity of 0.5% and mean grain size of 1.21μm was obtained at a co-doped content of 0.35wt.% of ZrO2 and MgO (mass ratio of 1:1). The co-dopants led to the enhanced hardness and bending strength as well as a favorable fracture toughness of the translucent alumina, when compared with the MgO single-doped and doping free samples. Moreover, total transmission of as high as 51% and good translucency was also obtained. The improved properties widened the prospect of the translucent alumina used as dental restorative materials.
La2Mo2O9 doped with cheap metal cations can further increase their conductivity. The transition metal element Mn and the rare-earth element Y co-doped La2Mo2O9-based electrolyte was used, and the sintered ceramic body La1.9Y0.1Mo 2−xMnxO 9−δ(x= 0∼0.4) was prepared by the sol-gel method, sintering at 950°C. The results show that the samples can suppress the phase transition and retain the β-phase of the structure of La2Mo2O9, due to doping, and it is a single pure phase, which has good sintering performance. Among them, La1.9Y 0.1Mo1.8Mn0.2O8.8 reached the maximum ionic conductivity of 0.0292 S⋅cm−1 at 800°C, and Ea is 0.425 eV, which can become a solid electrolyte material of IT-SOFC.
Nd/Pr co-doped Bi2WO6 photocatalytic materials were prepared via a simple one-step hydrothermal method. The physicochemical properties of the prepared samples were characterized by XRD, Raman, UV-Vis DRS, PL, SEM, BET analysis and photocatalytic tests. The results showed the co-dopants of Nd and Pr ions with the concentration of 1% Nd and 1% Pr exhibited the highest photocatalytic activity. Rhodamine B (RhB) was almost completely degraded within only 10 min. The increased photocatalytic activity on the co-doped Bi2WO6 is attributed to the increasing specific surface area, the inhibited recombination of photogenerated carriers and the reduced band gap energy. This study provides a helpful strategy for developing effective photocatalysts.