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We investigate fixed dopants in the presence of mobile point defects like foreign atoms or vacancies. A mobile defect entering the first Bohr radius R_B of a dopant will modulate the generation-recombination process. The times a defect walks inside or outside R_B are shown to be power-law distributed giving rise to 1 / f^b noise. The predicted Hooge coefficient α_def depends on R_B, on the normalized fluctuations of charge carriers and on the number of charge carriers compared to lattice sites; our model suggests that the magnitude of 1/f noise can be decreased at will by increasing the ionization of dopants.

We investigate fixed dopants in the presence of mobile point defects. A defect entering the first Bohr radius R_B of a dopant will modulate the generation-recombination (g-r) process. The times a defect walks inside and outside of R_B are found to be power-law distributed; correspondingly, the modulated g-r process exhibits 1/f^b noise. The predicted Hooge coefficient depends on R_B, on the normalized fluctuations of charge carriers, the number of lattice sites and on the modulation depth of the g-r process.

We show how defects in a spin chain described by the XXZ model may be used to generate entangled states, such as Bell and W states, and how to maintain them with high fidelity. We also discuss, in the presence of several excitations, how the anisotropy of the system may be combined with defects to effectively assist in the creation of the desired states.

In this paper we report on the preparation of nanobrushes of ZnO on quartz substrate by a direct atmosphere evaporation method using Zn metal flakes. Activated charcoal was used as a catalyst that facilitated the formation of nanobrushes in which the brush stem was about 15–20 μm in length and the bristles (100–200 nm thick) were made up of nanofibrous ZnO whose tips were 10–15 nm in width and were angled in some cases. These aligned nanobrushes can find potential applications as nanopower generators and high aspect ratio AFM probes by virtue of the piezoelectric property of ZnO. This technique is simple for realizing aligned ZnO nanobrushes with metallic Zn as the source material.

This research demonstrates the capability of controlled, focused ion beam (FIB)–assisted tailoring of morphologies in both multiwall carbon nanotubes (CNTs) and Y junction nonlinear CNT systems through defect engineering. We have shown that a 30 keV FIB Ga⁺ ion beam at low ion milling currents of 1 pA can be used to partially reduce the CNT diameter, to provide electrical conduction bottleneck morphologies for linear CNTs, and to introduce both additive and subractive defects at Y junction locations of Y-CNT samples. Our aim is for this work to provide motivation for additional research to determine the effects of ion-beam-induced changes in modulating the physical and chemical properties of nanotubes.

Nanocrystalline ZnO particles substituted with different concentrations (0–30%) of Mn were synthesized by using a modified ceramic route and characterized by X-ray diffraction, transmission electron microscopy, selected area electron diffraction and energy dispersive X-ray analysis methods. Positron lifetime and coincidence Doppler broadening measurements were used as probes to identify the vacancy-type defects present in them and monitor the changes while doping. The predominant positron trapping center in the undoped ZnO is identified as the trivacancy-type cluster V_Zn+O+Zn, which is negatively charged, and it transformed to the neutral divacancy V_Zn+O on doping with Mn²⁺ ions. The intensity of the defect-specific positron lifetime component got reduced initially indicating partial occupancy of the vacancies by the doped cations but then recovered on further doping due to the additional Zn vacancies created as a result of the increasing strain introduced by the Mn ions of larger radius. The creation of a new phase ZnMn₂O₄ thereafter changed the course of variation of the annihilation parameters, as the positrons got increasingly trapped in the vacancies at the tetrahedral and octahedral sites of the spinel nanomanganite.

We report room temperature ferromagnetism (RTFM) in nanocrystalline Zn_1-xCu_xO(0.03 ≤ x ≤ 0.07) materials synthesized by autocombustion technique. The average particle sizes are in the range of 60 nm. The saturation magnetization and coercivity of 7% Cu-doped ZnO is enhanced significantly in comparison to 3% and 5% Cu-doped ZnO. There is not much variation in the optical band gap due to Cu doping, thus suggesting the uniform distribution of Cu in the ZnO matrix. Micro-Raman and photoluminescence analysis predict the presence of clusters of oxygen vacancies in Cu-doped system which improves with the increase in Cu concentration. This study provides further evidence that oxygen vacancies play an important role in the enhancement of room temperature ferromagnetic property in Cu-doped ZnO.

Spherical Bi₂S₃ nanoparticles (NPs) were prepared by a facile in situ thermal sulfuration method. Different Bi₂S₃ samples were obtained by controlling the sulfuration time. The products were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), Raman and Fourier-transform infrared (FT-IR) methods. The optical properties were examined by UV-visible-near-infrared (UV-Vis–NIR) and photoluminescence (PL) techniques. The results show that the phase of the products after sulfuration is pure and the spherical shape of Bi NPs has been successfully transmitted to Bi₂S₃ samples. The light absorption edges exhibit red shift to 1060 nm while the light emission displays blue shift to 868 nm, compared with the energy bandgap of bulk Bi₂S₃. The reason for the special optical properties of Bi₂S₃ NPs by this in situ sulfuration route is considered to associate with the defects and quantum size effect of NPs.