Hemicellulose from dissolving pulp alkali extraction liquid was used as material for furfural production catalyzed by ZSM-5. Reaction temperature have significantly effect on furfural production. The optimal conditions for furfural production were 180 ºC, 1.5 g ZSM-5, 30 mL toluene for 2 h. Under the optimal conditions, furfural yield was 40.18%. When alkali extraction hemicellulose was hydrolyzed by enzyme (xylanase dosage 0.50 mL/g, 50ºC, 18 h) prior to ZSM-5 hydrolysis for furfural formation. The maximum furfural yield of 74.68% was achieved under the best reaction conditions. Furfural yield was effectively improved by enzyme hydrolysis of hemicellulose with high molecular weight.