The ballistic performance of Si and Ge nanowire (NW) is compared in this study. Current–voltage characteristic is obtained by self-consistently solving the nonequilibrium Green’s function (NEGF) transport equation with Poisson’s equation. The result is obtained at ⟨001⟩ channel orientation. Simulation result shows Ge NW gives higher ON-state current than Si NW, when OFF-state current is made equal by gate metal work function engineering. However, at subthreshold region, performance of NW FET for both material is almost identical. The intravalley and intervalley electron–phonon scattering effect is also calculated using the deformation potential theory and the self-consistent Born approximation. It is found that electron–phonon scattering effect is more pronounced at ON-state of Si NW FET. The ballistic current decreases with the decrease in diameter of the Si NW FET due to electron–phonon scattering.