Narrow Results

Creation of novel $\pi$-conjugated molecules is an important research topic. I describe in this account an approach to this aim that is based on the use of the distorted conformation of porphyrins. Planarization of distorted molecules enables the synthesis of heteroatom-containing porphyrin derivatives. Furthermore, dearomatization reaction proves effective to construct distorted conformations from planar $\pi$-conjugated molecules under mild reaction conditions. According to this protocol, we have succeeded in the synthesis of heteroatom-containing curved-$\pi$ conjugated molecules that had never been achieved by conventional protocols. In particular, a nitrogen-embedded buckybowl is the first example of a buckybowl having a heteroatom in its central position, which exhibits unique properties due to the incorporation of the heteroatom in its curved $\pi$-surface.

Single-walled carbon nanotubes (SWNTs) synthesized by catalytic decomposition of an alcohol were purified by extraction. The purified SWNTs were characterized on the basis of visible-near infrared (vis-NIR) absorption, photoluminescence and Raman spectroscopic analyses, scanning electron microscopy (SEM) observation, and thermal analysis. Selective extraction of metallic nanotubes was also achieved by the extraction condition.