Identification of aerosol type and chemical composition may help to trace their origin and estimate their impact on land and people. Aerosols chemical composition, size distribution and particles shape, manifest themselves in their spectral scattering cross-section. In order to make a reliable identification, comprehensive spectral analysis of aerosol scattering should be carried out. Usually, spectral LIDAR measurements of aerosols are most efficiently performed using an Nd:YAG laser transmitter in the fundamental frequency and its 2nd, 3rd and 4th harmonics. In this paper we describe automatic detection and identification of several aerosol types and size distributions, using a multispectral lidar system operating in the IR, NIR and UV spectral regions. The LIDAR transmitter is based on a single Nd:YAG laser. In addition to the 3rd and 4th harmonics in the UV, two optical parametric oscillator units produce the eye-safe 1.5 μm wavelength in the near IR and up to 40 separable spectral lines in the 8-11 μm IR. The combination of a wide spectral coverage required for backscattering analysis combined with fluorescence data, enable the generation of a large spectral data set for aerosols identification. Several natural and anthropogenic aerosol types were disseminated in controlled conditions, to test system capabilities. Reliable identification of transient and continuous phenomena demands fast and efficient control and detection algorithms. System performance, using the specially designed algorithms, is described below.