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  • articleNo Access

    THE CHANGES OF PHYSICAL PROPERTIES OF WATER ARISING FROM THE MAGNETIC FIELD AND ITS MECHANISM

    In this paper, the influences of magnetic field on electromagnetic properties of water are experimentally investigated. The results clearly show that the magnetic field reduces the dielectric constant and resistance of water and increases its electric conductivity. In this study, we also find that the electric conductivity of magnetized water increases with increasing the frequency of externally applied electromagnetic field and magnetized time, but its dielectric constant and resistance are decreased with increasing the frequency of electromagnetic field and magnetized time of water. Then we can affirm that the magnetic field changes the electric properties of water. Finally, we discuss the mechanism of variation of electromagnetic properties in water, which are due to the changes of nature of charged ions and velocity of hydrogen ions as well as the changes of polarized features or dipole moments of free molecules and clusters including linear and ring hydrogen-bond chains of molecules in water under the influences of electromagnetic fields. Therefore, this study has important significance in science and can expand the applications of magnetized water in biomedicine and industry.

  • articleNo Access

    Mechanism of enhanced photocatalytic activities on tungsten trioxide doped with sulfur: Dopant-type effects

    The enhanced photocatalytic activity of tungsten trioxide (WO3) has been observed experimentally via doping with S element as different dopant types. Herein, a comparative study on the effect of different types of S dopant and native vacancy defects on the electronic structure and optical properties of WO3 is presented by using hybrid Heyd–Scuseria–Ernzerhof 2006 (HSE06) density functional methods. Six possible models (SO–WO3, SW–WO3, VO–WO3, VW–WO3, SO + VW–WO3 and SW + VO–WO3) based on WO3 are tentatively put forward. It is found that cationic S doping (the substitution of W by S) is more favorable than anionic S doping (replacing O with S), and both cases become easier to form as native vacancy defect is accompanied. The electronic structures of doped WO3 depend on the type of dopant: anionic S doping results into three isolated levels in the upper part of valence band, while cationic S doping only induces an effective band gap reduction, which is critical for efficient light-to-current conversion. Interestingly, the isolated states near gap of WO3 would appear as long as native vacancy defects exist. The introduced levels or reduced band gaps make the systems responsed to the visible light, even further to a range of 400–700 nm. These findings can rationalize the available experimental results and pave the way for developing WO3-based photocatalysts.

  • articleNo Access

    Investigations on the effects of obstacles on the surfaces of blades of the centrifugal pump to suppress cavitation development

    This paper proposes a new method that obstacles are attached to both the suction and pressure surfaces of the blades to suppress cavitation development. A centrifugal pump with a specific speed of 32 is selected as the physical model to perform the external characteristic and cavitation performance experiments. SST kω turbulence model and Zwart cavitation model were employed to simulate the unsteady cavitation flow in the pump. The results indicate that the numerical simulation results are in good agreement with the experimental counterparts. After the obstacles are arranged, the maximum head decrease is only 1.37%, and the relative maximum drop of efficiency is 1.12%. Obstacles have minimal impacts on the variations of head and efficiency under all flow rate conditions. The distribution of vapor volume in the centrifugal pump is significantly reduced after obstacles are arranged and the maximum fraction reduction is 53.6%. The amplitude of blade passing frequency decreases significantly. While obstacles decrease the intensity of turbulent kinetic energy near the wall in the impeller passages to effectively reduce the distribution of cavitation bubbles, and control the development of cavitation. After the obstacles are set, the strength of the vortex in the impeller passages is weakened significantly, the shedding of the vortex is suppressed, flow in the impeller becomes more stable.

  • articleOpen Access

    SUPERPLASTIC BEHAVIOR OF COARSE-GRAINED Al-Mg ALLOY

    This paper concentrates on the study of the superplastic response of coarse-grained Al-Mg alloys under uniaxial tension at different temperatures (ranging from 400°C to 525°C) and strain rates (10-2 S-1, 10-3 S-1 & 10-4 S-1). The microstructures have been analyzed using optical (OM) and transmission electron microscopy (TEM). It has been observed that continuous re-crystallization occurs during hot deformation of the alloy at the temperature of 425°C and strain rate of 10-2S-1. At the temperature of 425°C and strain rate of 3.78×10-3S-1, this Al-Mg alloy has the maximum elongation to failure of 181%, which is sufficient for manufacturing of extremely complex shapes using superplastic forming technology. The constant strain rate sensitivity index m and TEM observations show that in this case deformation mechanism involved is dislocation glide. Recrystallization during the hot tension greatly enhanced the plasticity of the coarse-grained material at a strain rate of about 10-2S-1 and the maximum elongation changes as a function of the strain rate.