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We characterize rings over which every cotorsion module is pure injective (Xu rings) in terms of certain descending chain conditions and the Ziegler spectrum, which renders the classes of von Neumann regular rings and of pure semisimple rings as two possible extremes. As preparation, descriptions of pure projective and Mittag–Leffler preenvelopes with respect to so-called definable subcategories and of pure generation for such are derived, which may be of interest on their own. Infinitary axiomatizations lead to coherence results previously known for the special case of flat modules. Along with pseudoflat modules we introduce quasiflat modules, which arise naturally in the model-theoretic and the category-theoretic contexts.