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Towards chiral 1,2-naphthalocyanines: 2. Synthesis of lutetium bismacrocyclic derivatives

VOLODYA M. NEGRIMOVSKII

Organic Intermediates and Dyes Institute, B. Sadovoya, 1-4 Moscow, 103 787, Russia

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MARCEL BOUVET

ESPCI - CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France

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EVGENI A. LUK'YANETS

Organic Intermediates and Dyes Institute, B. Sadovoya, 1-4 Moscow, 103 787, Russia

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, and

JACQUES SIMON

ESPCI - CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France

Corresponding author, ESPCI - CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France.

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https://doi.org/10.1002/jpp.345Cited by:21 (Source: Crossref)

Abstract

Starting from 1,2-naphthalocyanine lutetium acetate (1,2-NcLuOAc) the unsymmetrical lutetium phthalo(naphthalo)cyanine (1,2-NcLuPc) has been synthesized and characterized by optical absorption spectra and fast atom bombardment (FAB) mass spectrometry. 1,2-Naphthalocyanine shows several geometrical isomers, both the mixture (noted Nc^∑) and one of them (Nc^Cs) have been used for forming the corresponding bismacrocycles. As a result the first racemic mixture of a chiral unsubstituted phthalo(naphthalo)cyanine complex has been synthesized and characterized.

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