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The rapid development of chemical enterprises has not only improved the material foundation of society, but also brought serious environmental and pollution problems. In order to provide decision-making basis for basic chemical enterprises to achieve green Supply Chain Management (SCM) and green innovation, the study proposes a hypothesis and conceptual model on the impact of green SCM on enterprise performance under the influence of green innovation. Measurement scales for each dimension are designed and a questionnaire survey is conducted. The reliability and validity of the sample data are examined in turn, the consistency of each dimension is determined through correlation analysis. Finally, a regression model is used to examine the correlation of the three variables. The results indicated that the cumulative total deviation variance explained by the dimensions of green supply chain innovation, business performance and green innovation in basic chemical enterprises were 80.101%, 77.425% and 74.526%, respectively. Green procurement had a significant negative impact on the performance of basic chemical enterprises. Green recycling and internal environmental management had a negative influence on enterprise performance. The research results contribute to promoting the sustainable development of chemical enterprises, providing new perspectives and methods for the practice of knowledge management, and offering guidance for chemical enterprises on how to better manage and apply knowledge, which is beneficial for the research and practice of knowledge management.