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In this paper, a hybrid electronic noses' system (HENS) based on MOS-SAW detection units intended for lung cancer diagnosis is proposed. The MOS gas sensors are used to detect the VOC molecules with low molecular weight (LMW), and the SAW sensors are adopted for the detection of VOC with high molecular weight (HMW). Thus, the novel combination of these two kinds of gas sensors provides higher sensitivities to more of VOC species in breath than that of using only a single kind of sensor. The signals from MOS-SAW detection units are then recognized by a multi-model diagnosis method. Applying four algorithms, six models were established for diagnosis and tested by leave-one-out cross-validation method. The model by artificial neural network (ANN) was selected as the best model to analyze breath samples. 89 clinical samples were tested with MOS-SAW ANN diagnostic model, which takes the features derived from both the MOS and SAW sensors. It shows the highest sensitivity of 93.62%, and the highest selectivity of 83.37%. The study shows that, promisingly, our HENS is effective during screening of lung cancer patients, especially among the people of high risk.
The effective utilisation of solar radiation requires the development of novel photocatalysts activated by visible-light. Activity tests of toluene decomposition were carried out in the presence of modified titanium dioxide photocatalysts in which some oxygen ions were substituted by sulfur. The elimination of toluene after 1 hour irradiation of the photocatalysts by a pulsed blue LED yielded 44 percent elimination. Pretreatment in which S-doped TiO2 was irradiated by UV for 1 hour prior to the activity test was effective in decomposing acetaldehyde, even under a pulsed green LED irradiation.
Dielectric barrier discharge plasma was used to oxidize trichloroethylene (TCE) in 21% of O2 in carriers of N2 and He. The degradation products of TCE were analyzed using gas chromatography mass spectrometry. TCE was decomposed completely at optimum energy density of 260 and 300 J/l for He and N2, respectively and its conversion followed zero order reaction. The TCE removal efficiency is decreased in humid air due to interception of reactive intermediates by OH radicals.