Search
This Journal
This Journal
Anywhere
Quick Search in Journals
Enter words / phrases / DOI / ISBN / keywords / authors / etc
Access type:Only show content I have full access toOnly show Open Access
Advanced Search
0 My Cart
Sign in
Institutional Access

System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Existing users will be able to log into the site and access content. However, E-commerce and registration of new users may not be available for up to 12 hours.
For online purchase, please visit us again. Contact us at customercare@wspc.com for any enquiries.

No Access

Synthesis and molecular structures of N,N-dialkyl-4-nitrosoaniline adducts of formally d⁶ metalloporphyrins of ruthenium and cobalt

Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA

Search for more papers by this author

,

JESSE B. FOX, JR

Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA

Search for more papers by this author

,

Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA

Search for more papers by this author

,

Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA

Search for more papers by this author

, and

GEORGE B. RICHTER-ADDO

Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA

Corresponding author, Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, OK 73019, USA.

Search for more papers by this author

https://doi.org/10.1002/jpp.382Cited by:7 (Source: Crossref)

Abstract

Para-aminosubstituted nitrosoarenes react with Ru(CO)(OEP) or [Co(TPP)(THF)₂]SbF₆ (OEP^2- = 2,3,7,8,12,13,17,18-octaethylporphyrinato dianion, TPP^2- = 5,10,15,20-tetraphenylporphyrinato dianion) to generate Ru(OEP)(ONC₆H₄NMe₂)₂ and [Co(TPP)(ONC₆H₄NR₂)₂]SbF₆ (R = Me, Et), respectively, in fair to high yields. These N-bound nitrosoarene complexes have been characterized by spectroscopic methods. The complexes Ru(OEP)(ONC₆H₄NMe₂)₂ and [Co(TPP)(ONC₆H₄NMe₂)₂]ClO₄ have also been characterized by single-crystal X-ray crystallography. Their structures represent the first reported solid-state structures of Ru and Co porphyrins containing C-nitroso ligands.

Keywords:

Most comprehensive & up-to-date research on PORPHYRINS
Handbook of Porphyrin Science now available in 46 volumes

References

Q. H. Gibson, Biochem. J. 77, 519 (1960). Crossref, Web of Science, Google Scholar
D. Mansuy, J. C. Chottard and G. Chottard, Eur. J. Biochem. 76, 617 (1977), DOI: 10.1111/j.1432-1033.1977.tb11632.x. Crossref, Google Scholar
J. M. Fukutoet al., Biochemistry 25, 2714 (1986), DOI: 10.1021/bi00357a065. Crossref, Web of Science, Google Scholar
D. Mansuyet al., J. Am. Chem. Soc. 105, 455 (1983), DOI: 10.1021/ja00341a027. Crossref, Web of Science, Google Scholar
N. Godboutet al., J. Am. Chem. Soc. 121, 3829 (1999), DOI: 10.1021/ja9832820. Crossref, Web of Science, Google Scholar
L.-S. Wanget al., Chem. Commun. 323 (1996), DOI: 10.1039/cc9960000323. Google Scholar
T. Sakuraiet al., Bull. Chem. Soc. Jpn. 49, 3042 (1976), DOI: 10.1246/bcsj.49.3042. Crossref, Web of Science, Google Scholar
(a) Buchler JW, Dreher C, Künzel FM. Struct. Bond. 1995; 84: 1–69.(b) Buchler JW, Dreher C, Künzel FM. Struct. Bond. 1995; 84: 24–25 . Google Scholar
I. M. Lorkovic and P. C. Ford, Inorg. Chem. 38, 1467 (1999), DOI: 10.1021/ic981121r. Crossref, Web of Science, Google Scholar
C. Crottiet al., Inorg. Chim. Acta 141, 13 (1988), DOI: 10.1016/S0020-1693(00)86366-5. Crossref, Web of Science, Google Scholar
L. Chenet al., Inorg. Chem. 37, 4689 (1998), DOI: 10.1021/ic980463u. Crossref, Web of Science, Google Scholar
K. Funatsuet al., Inorg. Chem. 36, 1625 (1997), DOI: 10.1021/ic961154b. Crossref, Web of Science, Google Scholar
G.-B. Yi, M. A. Khan and G. B. Richter-Addo, Inorg. Chem. 35, 3453 (1996), DOI: 10.1021/ic951600f. Crossref, Web of Science, Google Scholar
G.-B. Yi, M. A. Khan and G. B. Richter-Addo, Chem. Commun. 2045 (1996), DOI: 10.1039/cc9960002045. Google Scholar
G.-B. Yiet al., Inorg. Chem. 36, 3876 (1997), DOI: 10.1021/ic970282c. Crossref, Web of Science, Google Scholar
K. M. Kadish, Y. Hu and X. H. Mu, J. Heterocycl. Chem. 28, 1821 (1991). Web of Science, Google Scholar
B. R. Jameset al., Inorg. Chem. 27, 2414 (1988), DOI: 10.1021/ic00287a011. Crossref, Web of Science, Google Scholar
G.-B. Yiet al., Inorg. Chem. 37, 208 (1998), DOI: 10.1021/ic970957b. Crossref, Web of Science, Google Scholar
K. M. Mirandaet al., Inorg. Chem. 36, 4838 (1997), DOI: 10.1021/ic970065b. Crossref, Web of Science, Google Scholar
F. R. Hopfet al., J. Am. Chem. Soc. 97, 277 (1975), DOI: 10.1021/ja00835a008. Crossref, Web of Science, Google Scholar
S. Arielet al., Can. J. Chem. 62, 755 (1984), DOI: 10.1139/v84-127. Crossref, Web of Science, Google Scholar
R. Salzmannet al., J. Am. Chem. Soc. 121, 3818 (1999), DOI: 10.1021/ja9832818. Crossref, Web of Science, Google Scholar
J. Leeet al., Inorg. Chem. 38, 4578 (1999), DOI: 10.1021/ic990402b. Crossref, Web of Science, Google Scholar
H. Sugimoto, N. Ueda and M. Mori, Bull. Chem. Soc. Jpn. 54, 3425 (1981), DOI: 10.1246/bcsj.54.3425. Crossref, Web of Science, Google Scholar
S. J. Foxet al., Inorg. Chem. 36, 6465 (1997), DOI: 10.1021/ic970836b. Crossref, Web of Science, Google Scholar
H. Masudaet al., Bull. Chem. Soc. Jpn. 55, 4 (1982), DOI: 10.1246/bcsj.55.4. Crossref, Web of Science, Google Scholar
H. Banget al., J. Am. Chem. Soc. 114, 2843 (1992), DOI: 10.1021/ja00034a014. Crossref, Web of Science, Google Scholar
J.-P. Simonato, J. Pecaut and J.-C. Marchon, J. Am. Chem. Soc. 120, 7363 (1998), DOI: 10.1021/ja980644v. Crossref, Web of Science, Google Scholar
D. Torontoet al., Inorg. Chem. 37, 526 (1998), DOI: 10.1021/ic970995v. Crossref, Web of Science, Google Scholar
C. Richeet al., J. Chem. Res. 32, 534 (1978). Web of Science, Google Scholar
W. R. Scheidt, J. A. Cunningham and J. L. Hoard, J. Am. Chem. Soc. 95, 8289 (1973), DOI: 10.1021/ja00806a014. Crossref, Web of Science, Google Scholar
J. S. Summers, J. L. Petersen and A. M. Stolzenberg, J. Am. Chem. Soc. 116, 7189 (1994), DOI: 10.1021/ja00095a022. Crossref, Web of Science, Google Scholar
J. A. Kaduk and W. R. Scheidt, Inorg. Chem. 13, 1875 (1974), DOI: 10.1021/ic50138a017. Crossref, Web of Science, Google Scholar
Y. Iimura, T. Sakurai and K. Yamamoto, Bull. Chem. Soc. Jpn. 61, 821 (1988), DOI: 10.1246/bcsj.61.821. Crossref, Web of Science, Google Scholar
R. D. Arasasinghamet al., Inorg. Chem. 26, 3562 (1987), DOI: 10.1021/ic00268a029. Crossref, Web of Science, Google Scholar
W. Mikolaiskiet al., J. Organomet. Chem. 376, 397 (1989), DOI: 10.1016/0022-328X(89)85149-6. Crossref, Web of Science, Google Scholar
K. Yamamoto and Y. Iitaka, Chem. Lett. 697 (1989), DOI: 10.1246/cl.1989.697. Google Scholar
P. G. Jene and J. A. Ibers, Inorg. Chem. 39, 3823 (2000), DOI: 10.1021/ic000127p. Crossref, Web of Science, Google Scholar

Journal cover image

Vol. 05, No. 09

Metrics

Downloaded 34 times

History

Received 12 December 2000

Revised 11 May 2001

Accepted 16 May 2001

Keywords