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Dioxa-dithia Macrocycle-bridged Dimeric with Hexakis(alkylthio) Substituents and Network Polymer Phthalocyanines

A. G. GÜREK

Department of Chemistry, TÜBTAK Marmara Research Center, PO Box 21, 41470 Gebze, Kocaeli, Turkey

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and

Ö. BEKARO ĞLU

Department of Chemistry, Technical University of İstanbul, Maslak İstanbul, Turkey

To whom correspondence should be addressed.

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https://doi.org/10.1002/(SICI)1099-1409(199701)1:1<67::AID-JPP8>3.0.CO;2-RCited by:44 (Source: Crossref)

Abstract

1,7-dithia (12-crown-4)-bridged phthalocyanine network polymers were prepared from tetracyanodibenzo-[1,7-dithia(12-crown-4)]. In addition, the synthesis of two 1,7-dithia (12-crown-4) linked peripherally octa-substituted dimeric phthalocyanines, which contain a combination of hexakis(alkylthia) side chains, is described. These extremely soluble compounds were prepared by the condensation of an iminoisoindoline derivative and a subphthalocyanine. The novel compounds are characterized by elemental analyses, UV/vis, IR, mass, ¹H NMR and ¹³C NMR spectroscopy. The electrical conductivity measurements of three of the four network polymers were unsuccessful; however chemical doping with NOBF₄ could be increased to a measurable value. The electrical conductivity of the dimeric phthalocyanines are in the semiconductor range.

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Received 1 January 1996

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Dioxa-dithia Macrocycle-bridged Dimeric with Hexakis(alkylthio) Substituents and Network Polymer Phthalocyanines

Abstract

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System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Dioxa-dithia Macrocycle-bridged Dimeric with Hexakis(alkylthio) Substituents and Network Polymer Phthalocyanines

Abstract

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