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Synthesis of polymeric and low molecular weight phthalocyanines from nitriles and metal carbonyls on SiO₂ and TiO₂ and catalytic activities in the sulfide oxidation

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

Corresponding author, Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany.

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O. N. SUVOROVA

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP - 445, Russia

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N. TROMBACH

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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E. A. SCHUPAK

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP - 445, Russia

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R. GERDES

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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N. M. SEMENOV

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP - 445, Russia

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O. BARTELS

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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A. A. ZAKURAZHNOV

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP - 445, Russia

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G. SCHNURPFEIL

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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O. HILD

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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, and

A. WENDT

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330 440, 28334 Bremen, Germany

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https://doi.org/10.1002/jpp.334Cited by:18 (Source: Crossref)

Abstract

A new method for coatings of polymeric phthalocyanines and for comparison also of low molecular weight phthalocyanine metal complexes (W, Cr, Mo, Co) on quartz and titanium dioxide was developed by the reaction of metal carbonyls adsorbed on the carriers with tetracarbonitriles or phthalonitrile. By UV-vis or IR spectra the formation of structural uniform polymeric phthalocyanines on the carriers is established. The compounds are used then to compare their catalytic and photocatalytic activities in the oxidation of sulfide as test reaction.

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