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Synthesis of dihydroxy silicon phthalocyanine tetrasulfonic acid and poly-μ-oxo silicon phthalocyanine tetrasulfonic acid

A. G. GÜREK

TUBITAK-Marmara Research Center, Department of Chemistry, PO Box 21, 41470 Gebze-Kocaeli, Turkey

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G. APPEL

Brandenburgische Technische Universität Cottbus, Angewandte Physik-Sensorik, PO Box 101344, 03013 Cottbus, Germany

North Carolina State University, Physics Department, Box 7518, Raleigh, NC 27695, USA

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R. P. MIKALO

Brandenburgische Technische Universität Cottbus, Angewandte Physik-Sensorik, PO Box 101344, 03013 Cottbus, Germany

Corresponding author, Brandenburgische Technische Universität Cottbus, Angewandte Physik-Sensorik, PO Box 101344, 03013 Cottbus, Germany. Tel: +49 355 692998; Fax: +49 355 693931.

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, and

D. SCHMEIßER

Brandenburgische Technische Universität Cottbus, Angewandte Physik-Sensorik, PO Box 101344, 03013 Cottbus, Germany

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https://doi.org/10.1002/jpp.390Cited by:12 (Source: Crossref)

Abstract

We describe the synthesis of tetrasulfonated silicon phthalocyanine and its oligomer product prepared by metal salt catalyzed polycondensation. The catalytic effect of H₂O-free CaCl₂ in quinoline is used for the polycondensation of dihydroxy silicon phthalocyanine to the cofacially arrayed oligomer. Spectroscopic characterization and photoelectron spectroscopy data of the prepared compounds are reported. We present the first results on polypyrrole films doped with these substances.

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