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Phthalocyanine coatings on silica and zinc oxide: Synthesis and their activities in the oxidation of sulfide

Dieter Wöhrle

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330440, 28334 Bremen, Germany

Corresponding author.

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Natascha Baziakina

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP-445, Russia

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Olga Suvorova

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP-445, Russia

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Sergey Makarov

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP-445, Russia

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Valentina Kutureva

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP-445, Russia

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Elena Schupak

Russian Academy of Sciences, Institute of Organometallic Chemistry, Nizhnii Novgorod, GSP-445, Russia

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, and

Günter Schnurpfeil

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330440, 28334 Bremen, Germany

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https://doi.org/10.1142/S1088424604000751Cited by:15 (Source: Crossref)

Abstract

The reactivity of phthalonitrile, tetrafluorophthalonitrile and 4,5-dibutoxyphthalonitrile with unmodified surfaces of ZnO and SiO₂ and with the modified systems SiO₂/Cp₂Co, ZnO/Cp₂Co, SiO₂/Zn(AcAc)₂ prepared by deposition of cobaltocene (Cp₂Co) and zinc acetylacetonate Zn(AcAc)₂, was studied ("in-situ-synthesis") in processes of phthalocyanine coatings. The formation of structural uniform phthalocyanines on carriers were established by UV-vis and mass spectra. The compounds were used then to compare their catalytic and photocatalytic activities in the oxidation of sulfide as a test reaction.

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