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New model of dielectric strength of Debye relaxation in monohydroxy alcohols

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, Jiangsu 210093, P. R. China

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Xing-Yu Zhao

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, Jiangsu 210093, P. R. China

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Yi-Neng Huang

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, Jiangsu 210093, P. R. China

E-mail Address: ynhuang@nju.edu.cn

Corresponding author.

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https://doi.org/10.1142/S0217979219503132Cited by:3 (Source: Crossref)

Abstract

The Debye relaxation of dielectric spectroscopy exists extensively in monohydroxy alcohols, and the existing theory of the dielectric strength is obviously inconsistent with the experimental results. In this paper, we propose an Ising model of infinite free-rotating pseudospin chains and get the exact solution of the dielectric strength versus temperature. The model predictions are qualitatively consistent with the experimental results, especially the crossover from the low to the high-temperature Curie–Weiss law. The quantitative comparisons indicate that the model predictions can agree well with the experimental data below 250 K.

Keywords:

PACS: 77.22.−d, 82.30.Rs, 61.20.Gy, 77.22.Ch

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