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Ionic conductivity of monohydroxy alcohol liquids doped with known probe ions and analysis of the liquid structure

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, Jiangsu 210093, P. R. China

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

E-mail Address: 28908039@qq.com

Corresponding author.

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Li-Na Wang

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

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Xing-Yu Zhao

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

E-mail Address: xyzphys@163.com

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Yu-Fen He

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

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, and

Yi-Neng Huang

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, Jiangsu 210093, P. R. China

Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, P. R. China

E-mail Address: ynhuang@nju.edu.cn

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https://doi.org/10.1142/S0217979221500144Cited by:2 (Source: Crossref)

Abstract

The specific values of the conductivity $(σ)$ and its variation with temperature $(T)$ of 2-pentanol and 2-methyl-1-pentanol liquids doped with different concentrations of NaI (abbreviated as 2PEN- $x$ NaI and 2M1PEN- $x$ NaI, respectively) ( $x = 0 %$ , 1% and 5%) are measured by the commercial equipment. The results show that whether NaI is doped or not, $σ$ of 2PEN- $x$ NaI and 2M1PEN- $x$ NaI all have a conductivity peak in the range of 300–350 K different from that of typical glass-formers of small molecules. In addition, $σ$ goes up with increasing $x$ , and the temperature corresponding to $σ$ maximum increases with rising NaI content. Moreover, there is a nonlinear behavior of $σ$ with $x$ , i.e., with rising $x$ , $σ / x$ decreases at low-temperatures, but increases at high-temperatures. Moreover, the liquid structure and its variation with $T$ are further analyzed based on the ionic conductivity.

Keywords:

PACS: 66.10.x, 82.30.Rs, 64.70.P-, 77.22.Gm

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