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INVESTIGATION OF ADSORPTION AND INHIBITIVE EFFECT OF CALIXARENE DERIVATIVE NEWLY SYNTHESIZED TOWARDS C38 STEEL IN MOLAR HCl

R. SOUANE

Laboratoire de Chimie Appliquée et Environnement, Faculté des Sciences, Oujda, Morocco

ECPM, IPCH, UMR 7815 du CNRS-ULP, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France

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M. KADDOURI

Laboratoire de Chimie Appliquée et Environnement, Faculté des Sciences, Oujda, Morocco

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M. BOUKLAH

Laboratoire de Chimie Appliquée et Environnement, Faculté des Sciences, Oujda, Morocco

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N. CHERIAA

ECPM, IPCH, UMR 7815 du CNRS-ULP, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France

Faculté des Sciences de Bizerte, 7021, Zarouna-Bizerte, Tunisie

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B. HAMMOUTI

Laboratoire de Chimie Appliquée et Environnement, Faculté des Sciences, Oujda, Morocco

Corresponding author.

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, and

J. VICENS

ECPM, IPCH, UMR 7815 du CNRS-ULP, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France

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https://doi.org/10.1142/S0218625X09012780Cited by:2 (Source: Crossref)

Abstract

The focus of this study is to synthesize a new calixarene derivative namely calix[6]arene (C21) and to test its performance as corrosion inhibitor of C38 steel in molar HCl at 308 K. Polarization and weight loss measurements were used. Weight loss tests show that C21 retards until to stop corrosion phenomenon at 5 × 10^-5M. C21 is an excellent inhibitor and its inhibition efficiency increases with its concentration to reach 100% since 5 × 10^-5M. Polarization curves revealed that C21 affects both cathodic and anodic domains by decreasing current densities and then it may be classified as a mixed type inhibitor. The calixarene tested is adsorbed on the surface according to the Langmuir adsorption isotherm. Free enthalpy of adsorption reveals that C21 acts from chemisorption onto the steel surface.

Keywords:

References

C. D. Gutsche , Calixarenes ( The Royal Society of Chemistry , Cambridge , 1992 ) . Google Scholar
Z. Asfari et al. (eds.) , Calixarenes 2001 ( Kluwer Academic Publishers , Dordrecht, The Netherlands , 2001 ) . Crossref, Google Scholar
J. Harrowfield and J. Vicens (eds.) , Calixarenes in Nanochemistry ( Springer , Dordrecht, The Netherlands , 2007 ) . Google Scholar
L. Mandolini and R. Ungaro , Calixarenes in Action ( Imperial College Press , London, England , 2000 ) . Crossref, Google Scholar
C. Wieser, C. B. Deleman and D. Matt, Coord. Chem. Rev. 165, 93 (1997). Crossref, Web of Science, Google Scholar
G. J. Lumetta and R. D. Rogers , Calixarenes for Separations , ACS Symp. Series , ed. A. S. Gopalan ( 2000 ) . Crossref, Google Scholar
R. Ludwig, Fresenius J. Anal. Chem. 367, 103 (2000), DOI: 10.1007/s002160051611. Crossref, Google Scholar
L. Cecille , M. Carsarci and L. Pietrelli , New Separation Chemistry Techniques for Radioactive Wastes and Other Applications ( Elsevier Applied Sciences , London, England , 1991 ) . Crossref, Google Scholar
F. Arnaud, M. J. Schwing-Weill and J. F. Dozol, Calixarenes 2001, eds. Z. Asfariet al. (Kluwer Academic Publishers, Dordrecht, The Netherlands, 2001) pp. 642–662. Google Scholar
N. Cheriaa, R. Abidi and J. Vicens, J. Incl. Phenom. Macrocyclic Chem. 60, 303 (2008), DOI: 10.1007/s10847-007-9378-0. Crossref, Web of Science, Google Scholar
R. Bhaskaranet al., Anticorros. Meth. Mater. 52, 29 (2005), DOI: 10.1108/00035590510574899. Crossref, Web of Science, Google Scholar
M. V. Biezma and J. R. San Cristóbal, Corrosion 62, 1051 (2006). Crossref, Web of Science, Google Scholar
R. A. Bartschet al., J. Coord. Chem. 27, 75 (1992), DOI: 10.1080/00958979209407944. Crossref, Web of Science, Google Scholar
M. Abdallah and M. M. El-Naggar, Mater. Chem. Phys. 71, 291 (2001), DOI: 10.1016/S0254-0584(01)00289-9. Crossref, Web of Science, Google Scholar
J. O'M. Bockris, A. K. N. Reddy and M. Gamboa-Aldeco, Modern Electrochemistry, Fundamentals of Electronics, 2nd edn. (Kluwer Academic Publishers, 2002) p. 1025. Google Scholar
J. Cruzet al., J. Electroanal. Chem. 566, 111 (2004), DOI: 10.1016/j.jelechem.2003.11.018. Crossref, Web of Science, Google Scholar
M. A. Migahed, Prog. Org. Coat. 54, 91 (2005), DOI: 10.1016/j.porgcoat.2005.04.006. Crossref, Web of Science, Google Scholar
I. B. Obot and N. O. Obi-Egbedi, Colloids Surfaces A: Physicochem. Eng. Asp. 330, 207 (2008), DOI: 10.1016/j.colsurfa.2008.07.058. Crossref, Web of Science, Google Scholar
M. Benabdellahet al., Part I: Electrochemical Study. Mater. Chem. Phys. 105, 373 (2007). Crossref, Web of Science, Google Scholar
M. Bouklahet al., Prog. Org. Coat. 51, 118 (2004), DOI: 10.1016/j.porgcoat.2004.06.005. Crossref, Web of Science, Google Scholar
M. A. Quraishiet al., Brit. Corros. J. 32, 72 (1997). Crossref, Web of Science, Google Scholar
A. Popova, M. Christov and A. Zwetanova, Corros. Sci. 49, 2131 (2007), DOI: 10.1016/j.corsci.2006.10.021. Crossref, Web of Science, Google Scholar
V. S. Sastri, M. Elboujdaini and J. R. Perumareddi, Corrosion 61, 933 (2005). Crossref, Web of Science, Google Scholar
S. Elavarasan, K. Kannan and V. Chandrasekaran, Asian J. Chem. 18, 2637 (2006). Web of Science, Google Scholar
O. Benaliet al., Anti-Corrosion Methods Mat. 52, 280 (2005), DOI: 10.1108/00035590510615776. Crossref, Web of Science, Google Scholar
A. Dafaliet al., Ann. Chim. Sci. Mater. 25, 437 (2000), DOI: 10.1016/S0151-9107(00)80019-7. Crossref, Web of Science, Google Scholar
M. Kaddouriet al., J. Appl. Electrochem. 38, 1253 (2008), DOI: 10.1007/s10800-008-9546-y. Crossref, Web of Science, Google Scholar
M. Benabdellahet al., Pigm. Resin Techn. 36, 373 (2007), DOI: 10.1108/03699420710831791. Crossref, Web of Science, Google Scholar
S. A. Aliet al., Corros. Sci. 50, 3070 (2008), DOI: 10.1016/j.corsci.2008.08.011. Crossref, Web of Science, Google Scholar
F. Bentiss, M. Lebrini and M. Lagrenée, Corros. Sci. 47, 2915 (2005), DOI: 10.1016/j.corsci.2005.05.034. Crossref, Web of Science, Google Scholar
B. I. Ita and O. E. Offiong, Mat. Chem. Phys. 70, 330 (2001), DOI: 10.1016/S0254-0584(00)00476-4. Crossref, Web of Science, Google Scholar
A. A. Al-Sarawy, A. S. Fouda and W. A. S. El-Dein, Desalination 229, 279 (2008). Crossref, Web of Science, Google Scholar