Search
This Journal
This Journal
Anywhere
Quick Search in Journals
Enter words / phrases / DOI / ISBN / keywords / authors / etc
Access type:Only show content I have full access toOnly show Open Access
Advanced Search
0 My Cart
Sign in
Institutional Access

System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Existing users will be able to log into the site and access content. However, E-commerce and registration of new users may not be available for up to 12 hours.
For online purchase, please visit us again. Contact us at customercare@wspc.com for any enquiries.

Regular ArticlesNo Access

THERMODYNAMIC STUDY OF CORROSION AND INHIBITOR ADSORPTION PROCESSES ONTO C38 STEEL/PIPERAZINES/PHOSPHORIC ACID SYSTEMS

Corrections for this article
- ERRATA: "THERMODYNAMIC STUDY OF CORROSION AND INHIBITOR ADSORPTION PROCESSES ONTO C38 STEEL/PIPERAZINES/PHOSPHORIC ACID SYSTEMS"

Laboratoire de Chimie Solide Minérale, Faculté des Sciences, 60,000 Oujda, Morocco

Laboratoire de Chimie Appliquée & Environnement, Faculté des Sciences, 60,000 Oujda, Morocco

Search for more papers by this author

,

Laboratoire de Chimie Appliquée & Environnement, Faculté des Sciences, 60,000 Oujda, Morocco

Search for more papers by this author

,

Laboratoire de Chimie Solide Minérale, Faculté des Sciences, 60,000 Oujda, Morocco

Search for more papers by this author

,

Laboratoire de Chimie Appliquée & Environnement, Faculté des Sciences, 60,000 Oujda, Morocco

Search for more papers by this author

, and

Laboratoire de Chimie Appliquée & Environnement, Faculté des Sciences, 60,000 Oujda, Morocco

Search for more papers by this author

https://doi.org/10.1142/S0218625X09012949Cited by:8 (Source: Crossref)

Abstract

This paper describes the inhibition effect of 1-benzyl piperazine (P1) and bis(1-benzyl piperazine) thiuram disulfide (P2) towards the corrosion of C38 steel in 5.5 M H₃PO₄ solution by potentiodynamic polarization and weight loss methods. The influence of inhibitor concentration and temperature on inhibitory behavior of P2 were investigated. The inhibition efficiency (IE) was found to be dependent on the type of piperazine and its concentration. The IE for 10^-3 M P2 in 5.5 M H₃PO₄ is greater than 98%. Polarization studies clearly revealed that both P1 and P2 act as mixed-type inhibitors. Adsorption isotherms were fitted by the Langmuir isotherm. Adsorption energies ( and ) were evaluated. Kinetic parameters were determined.

An errata has been published. .

Keywords:

References

H. M. Seraget al., Sep. Purif. Technol. 61, 287 (2008). Web of Science, Google Scholar
H. Idrissiet al., Prog. Org. Coat. 63, 382 (2008), DOI: 10.1016/j.porgcoat.2008.06.011. Crossref, Web of Science, Google Scholar
I. Aydinet al., Microchem. J. 91, 63 (2009), DOI: 10.1016/j.microc.2008.08.001. Crossref, Web of Science, Google Scholar
M. A. Amin, Q. Mohsen and O. A. Hazzazi, Mater. Chem. Phys. 114, 908 (2009), DOI: 10.1016/j.matchemphys.2008.10.057. Crossref, Web of Science, Google Scholar
L. M. Alaouiet al., Port. Electrochin. Acta 26, 339 (2008). Crossref, Web of Science, Google Scholar
H. Ikenet al., Electrochim. Acta 52, 2580 (2007), DOI: 10.1016/j.electacta.2006.09.013. Crossref, Web of Science, Google Scholar
N. V. Likhanovaet al., Mater. Chem. Phys. 110, 344 (2008). Web of Science, Google Scholar
R. Souaneet al., Surf. Rev. Lett. 16, 401 (2009), DOI: 10.1142/S0218625X09012780. Link, Web of Science, ADS, Google Scholar
K. Tebbjiet al., Mater. Chem. Phys. 106, 260 (2007), DOI: 10.1016/j.matchemphys.2007.05.046. Crossref, Web of Science, Google Scholar
K. F. Khaled and N. Hackerman, Anti-Corros. Meth. Mater. 52, 11 (2005). Web of Science, Google Scholar
K. F. Khaled and N. Hackerman, Appl. Surf. Sci. 240, 327 (2005). Web of Science, Google Scholar
G. Bereket, J. Mol. Struct. Theochem. 663, 39 (2003), DOI: 10.1016/j.theochem.2003.08.062. Crossref, Web of Science, Google Scholar
A. Ousslimet al., J. Appl. Electrochem. 39, 1075 (2009), DOI: 10.1007/s10800-008-9759-0. Crossref, Web of Science, Google Scholar
I. Langmuir, J. Amer. Chem. Soc. 39, 1361 (1918). Web of Science, Google Scholar
Q. B. Zhang and Y. X. Hua, Electrochim. Acta 54, 1881 (2009), DOI: 10.1016/j.electacta.2008.10.025. Crossref, Web of Science, Google Scholar
E. E. Oguzieet al., Corros. Sci. 50, 3480 (2008). Crossref, Web of Science, Google Scholar
A. S. Fouda, l. Sarawy and l. Katori, Desalination 201, 1 (2006), DOI: 10.1016/j.desal.2006.03.519. Crossref, Web of Science, Google Scholar
B. Shaabani and D. Seifzadeh, Electrochim. Acta 50, 3446 (2005). Web of Science, Google Scholar
K. F. Khaled, Mater. Chem. Phys. 113, 150 (2009), DOI: 10.1016/j.matchemphys.2008.07.060. Crossref, Web of Science, Google Scholar
M. Lebriniet al., Corros. Sci. 50, 2914 (2008), DOI: 10.1016/j.corsci.2008.07.003. Crossref, Web of Science, Google Scholar
N. J. Ekpeet al., Mater. Chem. Phys. 40, 87 (1995), DOI: 10.1016/0254-0584(94)01464-R. Crossref, Web of Science, Google Scholar
M. H. Wahdan, Mater. Chem. Phys. 49, 135 (1997), DOI: 10.1016/S0254-0584(96)01925-6. Crossref, Web of Science, Google Scholar
A. E. Stoyanova, E. I. Sokolova and S. N. Raicheva, Corros. Sci. 39, 1995 (1997). Google Scholar
E. A. Noor, Corros. Sci. 47, 33 (2005), DOI: 10.1016/j.corsci.2004.05.026. Crossref, Web of Science, Google Scholar
E. E. Oguzie, Corros. Sci. 49, 1527 (2007), DOI: 10.1016/j.corsci.2006.08.009. Crossref, Web of Science, Google Scholar
M. Kaddouriet al., J. Appl. Electrochem. 38, 1253 (2008), DOI: 10.1007/s10800-008-9546-y. Crossref, Web of Science, Google Scholar
G. N. Mu, X. Li and F. Li, Mater. Chem. Phys. 86, 59 (2004), DOI: 10.1016/j.matchemphys.2004.01.041. Crossref, Web of Science, Google Scholar
B. Shabaniet al., Appl. Surf. Sci. 252, 4039 (2006). Web of Science, Google Scholar
A. Yurt, S. Ulutas and H. Dal, Appl. Surf. Sci. 253, 919 (2006), DOI: 10.1016/j.apsusc.2006.01.026. Crossref, Web of Science, ADS, Google Scholar
L. Herraget al., Acta Chim. Slov. 54, 419 (2007). Web of Science, Google Scholar
G. Gao and C. Liang, Electrochim. Acta 52, 4554 (2007), DOI: 10.1016/j.electacta.2006.12.058. Crossref, Web of Science, Google Scholar

Journal cover image

Vol. 16, No. 04

Metrics

Downloaded 19 times

History

Received 14 March 2009

Keywords