Evaluation of the optical, photoluminescence, and thermal characteristics of Barium thiourea chloride (BTCL), a metal–organic crystal for photonic applications
Abstract
The development of crystal fabrication and characterization approaches makes it possible to study novel materials with enhanced linear and nonlinear optical properties. The solution growth method was adopted in the present investigation to create Barium thiourea chloride (BTCL), a metal–organic single crystal. Structural, optical, and thermal characteristics of the BTCL crystals were evaluated by XRD analysis, Fourier transform infrared spectroscopy, UV–Vis spectrometry, photoluminescence, SHG, and thermal analyses. The XRD method was applied to investigate the structural characteristics of the BTCL, which is related to the monoclinic structure. The FT-IR spectral investigation was conducted to observe the vibrational modes in BTCL. The optical measurements showed the transmittance in the near-UV and visible spectrums. Optical characteristics include bandgap, refractive index, extinction coefficient, optical, and electrical conductivities, and dielectric constants were obtained. The PL curve showed two notable emission peaks at 482.5nm and 491nm. The ability to generate second harmonics was investigated using the Kurtz and Perry method, and the SHG was more than 1.79 times the KDP sample. The thermal behavior of the BTCL was evaluated by TGA/DTA measurements. The Coats–Redfern relation was used to estimate the activation energy of the thermal system and the value was determined to be 9.48KJ/mol. The findings indicate that the BTCL crystals possess excellent optical transparency, higher SHG potency, and good thermal stability, which are suitable for use in photonic structures.
