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Synthesis of glycosylated metal phthalocyanines and naphthalocyanines

Alexey Lyubimtsev

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Ivanovo State University of Chemistry and Technology, F. Engels str. 7, 15300 Ivanovo, Russia

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Zafar Iqbal

Karakoram International University, Department of Chemistry, Gilgit, Pakistan

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Göran Crucius

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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Sergey Syrbu

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Ivanovo State University of Chemistry and Technology, F. Engels str. 7, 15300 Ivanovo, Russia

SPP full member in good standing.

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Thomas Ziegler

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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, and

Michael Hanack

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Corresponding author, tel: +49 7071-2972432, fax: +49 7071-295268.

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https://doi.org/10.1142/S1088424612300030Cited by:15 (Source: Crossref)

Abstract

The first part of this review summarizes methods for the syntheses of mono-, di-, and tetra-substituted glycosylated phthalonitriles, which are the main starting materials for the preparation of the corresponding glycosylated metal phthalocyanines. In the second part the preparation of symmetrically and unsymmetrically tetra- and octa- glycosylated zinc phthalocyanines in which the sugar is attached either anomerically or via another one of its OH-groups to the phthalocyanine macrocycle as well as other structurally different glycosylated metal phthalocyanines are reviewed.

Dedicated to Professor Emanuel Vogel in memoriam

Keywords:

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