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Heteroleptic μ-nitrido diiron complex supported by phthalocyanine and octapropylporphyrazine ligands: Formation of oxo species and their reactivity with fluorinated compounds

Institut de Recherches sur la Catalyse et l’Environnement de Lyon, IRCELYON, UMR 5256, CNRS-Universitè Lyon 1, 2 av. Albert Einstein, 69626 Villeurbanne Cedex, France

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Evgeny V. Kudrik

Institut de Recherches sur la Catalyse et l’Environnement de Lyon, IRCELYON, UMR 5256, CNRS-Universitè Lyon 1, 2 av. Albert Einstein, 69626 Villeurbanne Cedex, France

Ivanovo State University of Chemistry and Technology 7, av F. Engels; 153000 Ivanovo, Russia

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Alexander B. Sorokin

Institut de Recherches sur la Catalyse et l’Environnement de Lyon, IRCELYON, UMR 5256, CNRS-Universitè Lyon 1, 2 av. Albert Einstein, 69626 Villeurbanne Cedex, France

E-mail Address: alexander.sorokin@ircelyon.univ-lyon1.fr

Corresponding author, fax: +33 472-445-399; tel:+33 472-445-337

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https://doi.org/10.1142/S1088424617500274Cited by:14 (Source: Crossref)

Abstract

The synthesis and reactivity of $N$ -bridged diiron macrocyclic complexes have been a topic of increasing interest in recent years since the observation of particular catalytic properties of these complexes. Herein, we report a preparation of a novel heteroleptic μ-nitrido diiron complex with unsubstituted phthalocyanine and octapropylporphyrazine macrocycles. This complex reacts with $m$ -chloroperbenzoic acid to form high-valent diiron oxo species showing strong oxidizing properties. The formation and structure of the transient oxo species was investigated by cryospray collision induced dissociation MS/MS technique. Analysis of fragmentation pattern showed that the attachment of oxo moiety occurred at either iron phthalocyanine or at iron porphyrazine site with slight preference for the phthalocyanine iron site. The catalytic properties of the heteroleptic μ-nitrido diiron complex were evaluated in the oxidative transformation of hexafluorobenzene and perfluoro(allylbenzene).

Dedicated to Professor Claudio Ercolani on the occasion of his 80th birthday

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