Electrocatalytic oxidation of petroleum, toluene and xylene on the Ni-porphyrin-modified graphite electrode
Abstract
In this study, electrochemical oxidation of petroleum was performed for the first time. Since petroleum is a rich source of hydrocarbons, its oxidation and electron production resulting in the production of electricity which is green energy is much more efficient than burning it. Electrochemical oxidation of petroleum with Ni-porphyrin-modified graphite electrode in alkaline media and by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) techniques were investigated. Due to the existence of two aqueous and organic phases, adsorption played a vital role in the process. To further confirm the accuracy of petroleum electrooxidation, electrooxidation of its compounds such as xylene and toluene was performed with the Ni-porphyrin electrode and by the mentioned techniques, which confirmed the previous data.
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