Rapid Structural Improvement of CVD-Grown Multi-Walled Carbon Nanotubes by Drastic Thermite Reaction
Abstract
Multi-walled carbon nanotubes (MWCNTs) produced by chemical vapor deposition (CVD) are the most common commercial products at extremely low price in the market. However, due to the inherent drawbacks of CVD surroundings at temperature below ∼∼1000∘∘C, CVD-grown nanotubes usually have very disordered structure, resulting in most of their properties being much below expectations. Herein, we present a simple and energy-efficient method for improving rapidly the structure of CVD-grown MWCNTs via a drastic thermite reaction process. Direct observations from scan electron microscope (SEM) and transmission electron microscope (TEM) images, decrease of ID∕IGID∕IG ratios in Raman spectra, increase of the starting oxidation temperatures observed in thermogravimetric analysis (TGA), decrease of the volumetric electrical resistivity and decrease of the turn-on electric fields from 3.64 to 2.88V/μμm in field emission measurements suggest that the graphitization of MWCNTs can be effectively enhanced and the structure of nanotubes becomes more ordered after the drastic thermite reaction process.
