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Amorphous Bimetallic Nanowires with High-Performance Microwave Absorption: A Case for FeCo Nanowires

National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, No. 2 YiKuang Street, Harbin 150080, P. R. China

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Yongtao Yao

National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, No. 2 YiKuang Street, Harbin 150080, P. R. China

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Yanju Liu

Department of Astronautical Science and Mechanics, Harbin Institute of Technology, No. 92 West Dazhi Street, Harbin 150001, P. R. China

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, and

Jinsong Leng

http://orcid.org/0000-0001-5098-9871

National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, No. 2 YiKuang Street, Harbin 150080, P. R. China

E-mail Address: lengjs@hit.edu.cn

Corresponding author.

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https://doi.org/10.1142/S1793292019500413Cited by:12 (Source: Crossref)

Abstract

Amorphous FeCo nanowires (NWs) with the average diameter of 120nm were successfully prepared with a magnetic-field-assisted (MFA) hydrothermal method. Rapid reaction time was adopted to obtain amorphous FeCo NWs, being checked by XRD and TEM. Tuning the stoichiometric ratio of Fe/Co content meets the optimal impedance matching under different absorption frequency, making both improved intensities and frequency ranges of microwave absorption. For example, under 3mm coating thickness, the reflection loss (RL) peaks of Fe₃Co₇, Fe₅Co₅ and Fe₇Co₃ NWs are $-$ $-$ 25.88dB at 4GHz, $-$ $-$ 19.06dB at 4.24GHz and $-$ $-$ 21.98dB at 5.44GHz. The related efficient absorption bandwidths ( $f_{E} < -$ $f_{E} < -$ 10 dB) of Fe₃Co₇ NWs, Fe₅Co₅ NWs and Fe₇Co₃ NWs are 5.40GHz, 3.52GHz and 4.91GHz, respectively. It is ascribed to integrating enhanced dielectric/conductive losses, negligible damages from eddy current effect and good impedance matching for high-performance FeCo NWs absorbers. This work paves a new path on synthesizing bimetallic wire-like nanostructures for microwave absorption demands.

Keywords:

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