EFFECT OF EPITAXIAL STRAIN ON THE STRUCTURAL AND FERROELECTRIC PROPERTIES OF Bi2FeCrO6 THIN FILMS
Abstract
Bi2FeCrO6 thin films were epitaxially grown by pulsed laser deposition on (100)-oriented LaAlO3, (LaAlO3)0.3(Sr2LaTaO6)0.7 and SrTiO3 single crystalline substrates with and without epitaxial CaRuO3 buffered layer. The in-plane compressive strain induces monoclinic distortion of the Bi2FeCrO6 lattice cell. The strain originates from lattice mismatch between CaRuO3 and single crystal substrates. The similar crystal structure of the substrate and the layer lead to coherent epitaxial growth of the heterostructures and avoid strain relaxation in particular for BFCO films deposited on LaAlO3 substrates. The ferroelectric character is demonstrated for all grown BFCO films. The residual in-plane strain weakly affects the effective piezoelectric coefficient of BFCO layers.