World Scientific
  • Search
  •   
Skip main navigation

Cookies Notification

We use cookies on this site to enhance your user experience. By continuing to browse the site, you consent to the use of our cookies. Learn More
×

System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Existing users will be able to log into the site and access content. However, E-commerce and registration of new users may not be available for up to 12 hours.
For online purchase, please visit us again. Contact us at [email protected] for any enquiries.

Ultralow switching voltage and power consumption of GeS2 thin film resistive switching memory

    https://doi.org/10.1142/S2010135X21500041Cited by:11 (Source: Crossref)

    The coming Big Data Era requires progress in storage and computing technologies. As an emerging memory technology, Resistive RAM (RRAM) has shown its potential in the next generation high-density storage and neuromorphic computing applications, which extremely demand low switching voltage and power consumption. In this work, a 10 nm-thick amorphous GeS2 thin film was utilized as the functional layer of RRAM in a combination with Ag and Pt electrodes. The structure and memory performance of the GeS2-based RRAM device was characterized — it presents high on/off ratio, fast switching time, ultralow switching voltage (0.15 V) and power consumption (1.0 pJ and 0.56 pJ for PROGRAM and ERASE operations, respectively). We attribute these competitive memory characteristics to Ag doping phenomena and subsequent formation of Ag nano-islands in the functional layer that occurs due to diffusion of Ag from electrode into the GeS2 thin film. These properties enable applications of GeS2 for low energy RRAM device.

    References

    • 1. H.-Y. Chen et al., Resistive random access memory (RRAM) technology: From material, device, selector, 3D integration to bottom-up fabrication, J. Electroceram. 39, 21 (2017). CrossrefGoogle Scholar
    • 2. M. Lanza et al., Recommended methods to study resistive switching devices, Adv. Electron. Mater. 5, 1800143 (2019). CrossrefGoogle Scholar
    • 3. D. Kuzum, S. Yu and H.-S. Philip Wong , Synaptic electronics: Materials, devices and applications, Nanotechnology 24, 382001 (2013). CrossrefGoogle Scholar
    • 4. I. Valov et al., Nanobatteries in redox-based resistive switches require extension of memristor theory, Nat. Commun. 4, 1771 (2013). CrossrefGoogle Scholar
    • 5. X. Hong et al., Oxide-based RRAM materials for neuromorphic computing, J. Mater. Sci. 53, 8720 (2018). CrossrefGoogle Scholar
    • 6. J. R. Jameson et al., (Invited) Conductive Bridging RAM (CBRAM): Then, now, and tomorrow, ECS Trans. 75, 41 (2016). CrossrefGoogle Scholar
    • 7. I. Valov , Interfacial interactions and their impact on redox-based resistive switching memories (ReRAMs), Semicond. Sci. Technol. 32, 093006 (2017). CrossrefGoogle Scholar
    • 8. H.-S. P. Wong et al., Metal–oxide RRAM, Proc. IEEE 100, 1951 (2012). CrossrefGoogle Scholar
    • 9. T. Ohno et al., Short-term plasticity and long-term potentiation mimicked in single inorganic synapses, Nat. Mater. 10, 591 (2011). CrossrefGoogle Scholar
    • 10. J. R. Jameson et al., Conductive-bridge memory (CBRAM) with excellent high-temperature retention, 2013 IEEE Int. Electron Devices Meeting (IEEE, 2013), pp. 30.1.1–30.1.4, https://doi.org/10.1109/IEDM.2013.6724721. CrossrefGoogle Scholar
    • 11. G. Palma et al., Experimental investigation and empirical modeling of the set and reset kinetics of Ag-GeS2 conductive bridging memories, 2012 4th IEEE Int. Memory Workshop (IEEE, 2012), pp. 1–4, https://doi.org/10.1109/IMW.2012.6213680. CrossrefGoogle Scholar
    • 12. F. Longnos et al., On the impact of Ag doping on performance and reliability of GeS2-based conductive bridge memories, Solid-State Electron. 84, 155 (2013). CrossrefGoogle Scholar
    • 13. G. Palma et al., Interface engineering of Ag-GeS2-based conductive bridge RAM for reconfigurable logic applications, IEEE Trans. Electron Devices 61, 793 (2014). CrossrefGoogle Scholar
    • 14. Y. Murakami and M. Wakaki , Observation of Ag photodoping phenomena in GeS2 chalcogenide glass films by spectroscopic ellipsometry and atomic force microscopy, Thin Solid Films 542, 246 (2013). CrossrefGoogle Scholar
    • 15. M. Mitkova and M. N. Kozicki , Silver incorporation in Ge–Se glasses used in programmable metallization cell devices, J. Non-Crystalline Solids 299–302, 1023 (2002). CrossrefGoogle Scholar
    • 16. H. Horton, K. L. Peatt and R. M. Lambert , Surface photo-oxidation and Ag deposition on amorphous GeS2, J. Phys.: Condens. Matter 5, 9037 (1993). CrossrefGoogle Scholar
    • 17. S. I. Sadovnikov and E. Yu. Gerasimov , Direct TEM observation of the “acanthite α-Ag 2 S–argentite β-Ag2 S” phase transition in a silver sulfide nanoparticle, Nanoscale Adv. 1, 1581 (2019). CrossrefGoogle Scholar
    • 18. J. Lee and W. D. Lu , On-demand reconfiguration of nanomaterials: When electronics meets ionics, Adv. Mater. 30, 1702770 (2018). CrossrefGoogle Scholar
    • 19. F. Pan et al., Nonvolatile resistive switching memories-characteristics, mechanisms and challenges, Prog. Nat. Sci.: Mater. Int. 20, 1 (2010). CrossrefGoogle Scholar
    • 20. R. Waser, R. Dittmann, G. Staikov and K. Szot , Redox-based resistive switching memories - Nanoionic mechanisms, prospects, and challenges, Adv. Mater. 21, 2632 (2009). CrossrefGoogle Scholar
    • 21. K. Onlaor, T. Thiwawong and B. Tunhoo , Electrical switching and conduction mechanisms of nonvolatile write-once-read-many-times memory devices with ZnO nanoparticles embedded in polyvinylpyrrolidone, Org. Electron. 15, 1254 (2014). CrossrefGoogle Scholar
    • 22. J. van den Hurk, V. Havel, E. Linn, R. Waser and I. Valov , Ag/GeSx/Pt-based complementary resistive switches for hybrid CMOS/Nanoelectronic logic and memory architectures, Sci. Rep. 3, 2856 (2013). CrossrefGoogle Scholar
    • 23. E. Linn, S. Menzel, S. Ferch and R. Waser , Compact modeling of CRS devices based on ECM cells for memory, logic and neuromorphic applications, Nanotechnology 24, 384008 (2013). CrossrefGoogle Scholar
    • 24. E. Linn, R. Rosezin, C. Kügeler and R. Waser , Complementary resistive switches for passive nanocrossbar memories, Nat. Mater. 9, 403 (2010). CrossrefGoogle Scholar