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Dielectric and piezoelectric properties of modified lead-free NaNbO₃–KNbO₃/PVDF composite ceramics

Federal Research Centre, The Southern Scientific Centre of the Russian Academy of Sciences (SSC RAS), 41 Chekhova Street, Rostov-on-Don 344006, Russia

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

E-mail Address: yucomp@ya.ru

E-mail Address: yucomp@yandex.ru

Corresponding author.

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M. I. Tolstunov

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

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A. V. Nazarenko

Federal Research Centre, The Southern Scientific Centre of the Russian Academy of Sciences (SSC RAS), 41 Chekhova Street, Rostov-on-Don 344006, Russia

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A. A. Pavelko

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

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A. V. Yudin

Federal Research Centre, The Southern Scientific Centre of the Russian Academy of Sciences (SSC RAS), 41 Chekhova Street, Rostov-on-Don 344006, Russia

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

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I. A. Verbenko

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

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, and

L. A. Reznitchenko

Southern Federal University, 105/42 Bolshaya Sadovaya Street, Rostov-on-Don 344006, Russia

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https://doi.org/10.1142/S2010135X21600158Cited by:13 (Source: Crossref)

This article is part of the issue:

Special Issue on the 2020 International Conference on Physics and Mechanics of New Materials and Their Applications (PHENMA-2020) — Part 1
Guest Editors: Ivan A. Parinov, Shun-Hsyung Chang, Yun-Hae Kim and Nao-Aki Noda

Abstract

This work presents the results of study of the electrophysical properties of composite polymer ceramics (1 $- x)$ [KNN-LTSN]– $x$ PVDF at $x$ = 25 vol.% and $x$ = 50 vol.% in the temperature range of $T$ = 20–160 $^{\circ}$ C and frequency range of $f$ = 2 × 10¹–2 × 10⁶ Hz. The concentration dependence of piezomodules of the studied materials has been analyzed as a function of temperature. X-ray measurements have also been carried out. A model of description of revealed dielectric parameters dispersion in the material is presented. The nonclassical modified Havriliak–Negami model written for complex electrical conductivity has been used to describe the temperature–frequency properties. It is shown that the dielectric spectra of the studied composites include three relaxation processes in the temperature ranges of 40–80 $^{\circ}$ C, 80–120 $^{\circ}$ C and 120–150 $^{\circ}$ C, which were confirmed by the dynamics of changes in the dependences of ${γ^{'}}^{(} f)$ , tg $δ (f)$ , ${M^{'}}^{(} f)$ , $M^{′′}$ ( $f$ ) and $M ′′$ ( $M')$ . All three processes are almost exactly described by this model and well correlated with the studies by other researchers of the composites based on PVDF. The results of this work show that the use of such experimental model is suitable for describing the complex dielectric spectra of any nonlinear dielectrics including composite materials.

Keywords:

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Vol. 11, No. 05

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History

Received 14 April 2021

Revised 3 June 2021

Accepted 21 June 2021

Published: 18 August 2021

Information

This is an Open Access article published by World Scientific Publishing Company. It is distributed under the terms of the Creative Commons Attribution 4.0 (CC BY) License which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Dielectric and piezoelectric properties of modified lead-free NaNbO3–KNbO3/PVDF composite ceramics

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Dielectric and piezoelectric properties of modified lead-free NaNbO₃–KNbO₃/PVDF composite ceramics