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Synthesis and properties of axially substituted zirconium(IV) and hafnium(IV) phthalocyanines with organic ligands

L. A. TOMACHYNSKI

Institute of General and Inorganic Chemistry, Prospect Palladina 32/34, Kiev, Ukraine

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V. YA. CHERNII

Institute of General and Inorganic Chemistry, Prospect Palladina 32/34, Kiev, Ukraine

Corresponding author, Institute of General and Inorganic Chemistry, Prospect Palladina 32/34, Kiev, Ukraine.

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, and

S. V. VOLKOV

Institute of General and Inorganic Chemistry, Prospect Palladina 32/34, Kiev, Ukraine

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https://doi.org/10.1002/jpp.384Cited by:20 (Source: Crossref)

Abstract

Water-soluble phthalocyaninato zirconium(IV) and hafnium(IV) complexes have been synthesized for the first time. An increased solubility in comparison to PcZrCl₂ and PcHfCl₂ was caused by the introduction of gallic, 1,8-dihydroxynaphthalene-3,6-disulfonic (chromotropic), and 5-sulfosalicylic acids in the axial position. The new compounds were characterized by ¹H NMR, IR, UV-vis and elemental analysis.

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References

C. C. Leznoff and A. B. P. Lever , Phthalocyanines: Properties and Applications 1–4 ( VCH , New York , 1996 ) . Google Scholar
F. H. Mozer and A. L. Thomas , The Phthalocyanines ( CRC Press , Boca Raton, FL , 1983 ) . Google Scholar
D. T. Mowry, Chem. Rev. 42, 189 (1948), DOI: 10.1021/cr60132a001. Crossref, Web of Science, Google Scholar
M. Hanack and H. Heckmann, Eur J. Inorg. Chem. 367 (1998). Google Scholar
N. A. Kostrominaet al., Zh. Inorg. Khim. 40, 1491 (1995). Google Scholar
D. Dolphinet al., Can. J. Chem. 58, 1125 (1980), DOI: 10.1139/v80-175. Crossref, Web of Science, Google Scholar
O. V. Dolotovaet al., J. Porphyrins Phthalocyanines 1, 355 (1997). Link, Web of Science, Google Scholar
J. Metz and M. Hanack, Chem. Ber. 121, 231 (1988), DOI: 10.1002/cber.19881210206. Crossref, Google Scholar
G. A. Kraus and S. J. Vander Louw, Synlett 8, 726 (1996). Google Scholar
(a) Decreau R, Chanon M, Julliard M. Synlett. 1998; 4: 375. (b) Brewis M, Clarkson GJ, Goddard V, Helliwell M, Holder AM, McKeown NB. Angew. Chem. Int. Ed. 1998; 37: 1092 . Google Scholar
R. D. Yoyner and M. E. Kenney, J. Chem. Soc. 5790 (1961). Google Scholar
E. Agaret al., Dyes Pigm. 36, 407 (1998), DOI: 10.1016/S0143-7208(97)00021-1. Crossref, Web of Science, Google Scholar
Ts. B. Konunova , Coordinated Compounds of Zirconium and Hafnium with Organic Ligands ( Shtiintsa Press , Kishenev , 1975 ) . Google Scholar
V. L. Goedkenet al., Inorg. Chem. 24, 991 (1985), DOI: 10.1021/ic00201a006. Crossref, Web of Science, Google Scholar
L. A. Tomachynski, V. Ya. Chernii and S. V. Volcov, Ukr. Khim. Zh. 66, 5 (2000). Google Scholar
M. Barthel and M. Hanack, Porphyrins J. Phthalocyanines 4, 635 (2000). Link, Web of Science, Google Scholar
Z. Gorschet al., Z. Anorg Allg. Chem. 621, 607 (1995), DOI: 10.1002/zaac.19956210418. Crossref, Web of Science, Google Scholar
R. Guilardet al., Inorg. Chem. 34, 1472 (1995), DOI: 10.1021/ic00110a027. Crossref, Web of Science, Google Scholar
R. D. Georgeet al., J. Porphyrins Phthalocyanines 2, 1 (1998). Link, Web of Science, Google Scholar