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Synthesis of new side-chain phthalocyanine methacrylate monomers for ophthalmosurgery in ophthalmology

Russian Academy of Sciences, Institute of Organometallic Chemistry, GSP-445, Tropinina str.49, 603950 Nizhnii Novgorod, Russia

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Natascha Baziakina

Russian Academy of Sciences, Institute of Organometallic Chemistry, GSP-445, Tropinina str.49, 603950 Nizhnii Novgorod, Russia

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Ksenia Maximova

Russian Academy of Sciences, Institute of Organometallic Chemistry, GSP-445, Tropinina str.49, 603950 Nizhnii Novgorod, Russia

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Valentina Morozova

NPP REPER-NN, 23-7, pr. Gagarina, 37, 603009 Nizhnii Novgorod, Russia

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Günter Schnurpfeil

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330440, 28334 Bremen, Germany

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Dieter Wöhrle

Universität Bremen, Institut für Organische und Makromolekulare Chemie, P.O. Box 330440, 28334 Bremen, Germany

Corresponding author, fax: +49 421-2184935.

SPP full member in good standing.

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, and

Olga Suvorova

Russian Academy of Sciences, Institute of Organometallic Chemistry, GSP-445, Tropinina str.49, 603950 Nizhnii Novgorod, Russia

Corresponding author.

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https://doi.org/10.1142/S1088424608000212Cited by:3 (Source: Crossref)

Abstract

Convenient synthesis of new methacryloyloxy-substituted phthalocyanines for polymerization reactions, i.e. copper(II) 2,9,16,23-tetra(methacryloxyethoxycarbonyl)phthalocyanine and copper 2,9,16-tris(tert-butyl)-23-(methacryloxyethoxycarbonyl)phthalocyanine, consisting of just a few steps, has been developed. The copolymerization with a dimethacrylate derivative was investigated. The substituted phthalocyanines are interesting materials for ophthalmosurgery in ophthalmology (contact vision correction of eye lenses).

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