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Convenient synthesis of new methacryloyloxy-substituted phthalocyanines for polymerization reactions, i.e. copper(II) 2,9,16,23-tetra(methacryloxyethoxycarbonyl)phthalocyanine and copper 2,9,16-tris(tert-butyl)-23-(methacryloxyethoxycarbonyl)phthalocyanine, consisting of just a few steps, has been developed. The copolymerization with a dimethacrylate derivative was investigated. The substituted phthalocyanines are interesting materials for ophthalmosurgery in ophthalmology (contact vision correction of eye lenses).