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INVESTIGATING THE EFFECT OF MCM-41 NANOPARTICLES ON THE KINETICS OF ATOM TRANSFER RADICAL POLYMERIZATION OF STYRENE

Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, P. O. Box 15875-4413, Tehran, Iran

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VAHID HADDADI-ASL

Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, P. O. Box 15875-4413, Tehran, Iran

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MEHDI SALAMI-KALAJAHI

Department of Polymer Engineering, Sahand University of Technology, P. O. Box 51335-1996, Tabriz, Iran

Institute of Polymeric Materials, Sahand University of Technology, P. O. Box 51335-1996, Tabriz, Iran

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MOHAMMADREZA SARSABILI

Department of Chemical Engineering, Gas, and Petroleum, Semnan University, P. O. Box 35131-19111, Semnan, Iran

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, and

HOSSEIN ROGHANI-MAMAQANI

Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, P. O. Box 15875-4413, Tehran, Iran

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https://doi.org/10.1142/S1793292013500185Cited by:8 (Source: Crossref)

Abstract

Effect of pristine and modified MCM-41 on the kinetics of styrene atom transfer radical polymerization (ATRP) was studied using a double bound containing modifier at 110°C. Conversion, molecular weight and PDI were obtained during the polymerization reactions to study the polymerization kinetics. Addition of the both types of MCM-41 has resulted in inconsiderable variations on the kinetics of polymerization. A similar trend is observed for the molecular weight of the free chains; however, increasing MCM-41 content results in higher PDI values. Also, surface modification of MCM-41 results in lower polymerization rates. In the case of grafted chains, molecular weight and PDI values increase by increasing MCM-41 content.

Keywords:

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