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Synthetic strategies towards functionalized N-bridged $μ$ -nitrido diiron porphyrin complexes

Gebze Technical University, Chemical Engineering Department, 41400 Gebze Kocaeli, Türkiye

Acıbadem Mehmet Ali Aydınlar University, Faculty of Engineering and Natural Sciences, Biomedical Engineering Department, Ataşehir, Istanbul, Türkiye

E-mail Address: fabienne.dumoulin@acibadem.com.tr

E-mail Address: dumoulin.fabienne@gmail.com

Corresponding authors.

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Ümit İşci

Gebze Technical University, Chemistry Department, 41400 Gebze Kocaeli, Türkiye

E-mail Address: u.isci@gtu.edu.tr

Corresponding authors.

SPP full member in good standing.

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https://doi.org/10.1142/S1088424623500268Cited by:0 (Source: Crossref)

Abstract

$N$ -bridged diiron porphyrinoid complexes are powerful oxidation biomimetic catalysts. Their use as oxidation catalysts is quite recent, as it started approximately one decade ago. Many mechanistic works and elucidation of properties are conducted on simple derivatives which are not functionalized, preventing their covalent incorporation into advanced materials, even though it would expand their scope of applications. With the ultimate purpose to produce $N$ -bridged diiron porphyrinoid complexes that can be incorporated into advanced functionalized materials and thereby increase the range of their utilization, we have explored synthetic strategies to prepare di- and octafunctionalised $N$ -bridged diiron porphyrin complexes, either with hydroxyl or propargyl functions, which have been selected for their versatility. The considerations taken into account for the synthetic strategies are detailed and the complexes are fully characterized.

Dedicated to Prof. Tomás Torres on the occasion of his 70^th birthday

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