This paper presents a formula for the a-number of certain maximal curves characterized by the equation yq+12=xm+x over the finite field 𝔽q2. a-number serves as an invariant for the isomorphism class of the p-torsion group scheme. By utilizing the action of the Cartier operator on H0(𝒳,Ω1), we establish a closed formula for the a-number of 𝒳.