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  • articleNo Access

    MAGNETORHEOLOGY OF CARBONYL-IRON SUSPENSION WITH IRON/MCM-41 ADDITIVE

    Iron containg hexagonal mesoporous silica particle (Fe-MCM-41) was prepared and adopted into carbonyl-iron (CI) based magnetorheological (MR) suspension as an additive to improve the sedimentation problem of the CI based MR fluid. Structural properties and morphology of the synthesized Fe-MCM-41 particles were observed using SEM. Their MR properties such as oscillation characteristics and flow response (shear stress and shear viscosity) were examined via a rotational rheometer in parallel plate geometry equipped with a magnetic field supplier under external magnetic field strengths ranging from 0 to 257 kA/m. The addition of Fe-containing mesoporous particles into CI suspension was found to improve not only MR behaviors but also sedimentation problem of the CI based MR fluid.

  • articleNo Access

    Preparation of silver nanoparticles and application in water-based conductive inks

    We reported a simple, high yield and large-scale preparation method for silver nanoparticles. Silver nanoparticles with 8–13 nm in diameter were successfully synthesized by silver nitrate as raw material, sodium borohydride as reducing agent, dispersan-5040 (polycarboxylate sodium salt) as surface modifier in aqueous solution. The effects of sodium borohydride and dispersan-5040 on the morphologies of silver nanoparticles were investigated. Further, the conductive inks were prepared with as-synthesized silver nanoparticles as conductive fillers in the presence of deionized (DI) water and additives. The effects of conductive fillers and additives on the pH, conductivity, surface tension and viscosity of the inks were investigated. The conductive patterns were fabricated by inkjet printer and their performances were studied. The sheet resistances of the printed pattern with seven-layer was 1.2 Ω/ when the printed pattern was heat-treated at 120C for 60 min. We succeeded in printing a simple conductive circuit on photographic paper, which can light three 0.06 W LED beads. The successful fabrication of the functional circuit proves the feasibility of the ink and provides some ideas for future paper-based circuits.

  • articleNo Access

    THE DESIGN OF SURFACE MODIFICATION OF AMORPHOUS ZrO2 NANOPARTICLES AS A LUBRICANT ADDITIVE

    ZrO2 is a kind of inorganic material with high hardness, high tenacity, antiwear, corrosion, and resistance, therefore it is regarded as an ideal nanolubricant material. But untreated ZrO2 nanoparticles are reunited in the lubricant medium instead of monodisperse because the consistency is poor between the material surface and lubricant, which restricts its application as a nanolubricant additive. Through theoretical analysis, this paper designed that the surface of ZrO2 nanoparticles was modified with silicon coupling agent, and it was changed to lipophilic surface, so it was possible to be a monodisperse system in the lubricant. The modified spherical nanoparticles of ZrO2 were dispersed in the lubricant and they could play a molecular bearing part in lubricating media. When the friction surface reached a certain load and temperature, once the metal surface produces the deficiency, physical adsorption and chemisorption on the metal surface would be produced because of high nano-ZrO2 particle activity, and even the N atom in the particle surface silane tends to be absorbed to the metal surface to form chelate compound, and make ZrO2 particles enrich to defective locations of the metal surface. Then, a self-repairing lubricated membrane in the friction surfaces was set up, and it can play the function in the antifriction, antiwear, and surface dynamic self-repair.

  • articleNo Access

    HYDROPHILIZATION OF POLYVINYL CHLORIDE SURFACE BY OZONATION

    The surface modification mechanism of polyvinyl chloride (PVC) by ozonation was investigated to study the selective hydrophilization of PVC surface among other plastics. Infrared analysis confirmed the increase of hydrophilic groups. XPS analysis revealed that the increase was due to the structural change in chlorine group in PVC to hydroxylic acid, ketone, and carboxylic groups by ozonation. This chemical reaction by ozone could occur only for polymers with chlorides in its structure and resulted in the selective hydrophilization of PVC among various polymers.

  • articleNo Access

    COMPARISON OF THE INFLUENCE OF PHYTIC ACID AND SILANE ADDITIVES ON CORROSION RESISTANCE OF CERAMIC COATINGS ON Mg ALLOY BY PEO METHOD

    Phytic acid (PA) and 3-aminopropyltrimethoxysilane (APTMS) were selected as organic additives and respectively doped into Na2SiO3-NaOH electrolyte to prepare ceramic coatings on AZ31B Mg alloys by Plasma Electrolytic Oxidation (PEO) method. The influences of two additives on corrosion resistance of the PEO coatings were compared. The microstructure, composition and corrosion resistance of the PEO coatings were examined by SEM, EDX, XPS, XRD, potentiodynamic polarization test and EIS measurement. The results indicated that each additive increased both the coating thickness and corrosion resistance. However, the PA-doped PEO coating achieves larger thickness but exhibits worse corrosion resistance than the APTMS-doped PEO coating due to larger pore size and looser microstructure.

  • articleNo Access

    EXPERIMENTAL ANALYSIS OF 3D PRINTED PALLET MODEL THROUGH FUSED DEPOSITION MODELING

    Disparate industry bodies across the planet use pallets for storing large and heavy objects. Pallets provide an assurance of safe handling of material (cargo) and storage of material in a damage-free environment. In this work, an attempt has been made to analyze and investigate making pallets out of ULTEM 9805 using the latest additive techniques (FDM). The maximum deflections and von Mises stresses are analyzed for the disparate boundary conditions indicating the possible alternatives or loads to be used. Study of surface (morphology) and characteristics was done in order to establish the relationship between pallet surface and its application. The factors of load, maximum and minimum values, ascertained in each stage are 168.15, 522.22, 215.31 and 316.79 kPa as well as 18.77, 6.7, 1.2 and 35.84 kPa for the floor, rack, forklift and conveyor load supports, respectively. A cross-hatched design causes a rise in capacity of the shear factor owing to the length of the span being in correlation with rectilinear fill. The filament of surface, made of ULTEM 9805, exhibits a level of roughness of 43.14 μm on the pallet surface indicating better holding capacity and grip. A 9 peak shift is comprehended with respect to XRD, indicating a compressive residual factor measured at 76.47 MPa.

  • articleNo Access

    A STUDY ON THE MICROSTRUCTURE, WEAR, AND INDENTATION TOUGHNESS OF ANODIZED ALUMINUM OXIDE LAYER MODIFIED WITH A NEW ADDITIVE

    In this study, lemon juice at different concentrations as a new additive was poured into the bath of the anodizing process to enhance the mechanical properties of the manufactured aluminum oxide layers. X-ray diffraction (XRD) and field-emission scanning electron microscopy were utilized to detect formed phases and microstructure, respectively. To investigate mechanical properties, microhardness, indentation toughness, and wear tests of various aluminum oxide layers were performed. The XRD patterns showed a crystalline phase of γ-Al2O3 for all oxide layers. The microhardness of modified layers increased up to 62.2% compared to the unmodified layer. However, by increasing the additive concentration to 2.5 vol%, the hardness decreased. This was based on increasing the pore size of layers. The lowest friction coefficient with a value of 0.53, the lowest wear rate, and the highest indentation toughness was also related to the modified aluminum oxide layer when the concentration of the additive in the bath was 0.3 vol%. For this modified layer, the value of COF/H was the lowest, and the pore size of 50 nm was the lowest among the layers.

  • articleNo Access

    DOUBLY STOCHASTIC EFFECTS

    Doubly stochastic effects are effects in which an optimization of both multiplicative and additive noise intensities is necessary to induce ordering in a nonlinear system. I review recent achievements in the investigation of these effects and discuss two phenomena: doubly stochastic resonance and noise-induced propagation in monostable medium. Finally I discuss possible experimental implementations of these phenomena.

  • articleNo Access

    COVALENTLY BONDING CHIRAL POLYURETHANE ON AMINATED SILICA GEL: A NEW STRATEGY TO PREPARE CHIRAL STATIONARY PHASE FOR HIGH PERFORMANCE LIQUID CHROMATOGRAPHY

    Two polyurethanes of different molecular weights were prepared by the copolymerization of phenyl diisocyanate and diisopropyl tartrate. The polyurethanes having terminal isocyanate groups were reacted with 3-aminopropyl silica gel to afford two chiral stationary phases. The formula of the two polyurethanes were 4057 g/mol and 6442 g/mol. The polyurethanes and the corresponding chiral stationary phases were characterized by FT-IR, 1H NMR and elemental analysis. The loading capacities of the polyurethanes on silica gel were 0.68 mmol units/g and 0.61 mmol units/g, respectively. The separation performance and the influence of additives, triethylamine and trichloroacetic acid, on the separation of chiral compounds were investigated by HPLC. The chiral stationary phase prepared from polyurethane with formula of 4057 g/mol demonstrated better enantioseparation capability than that with formula of 6442 g/mol. Additionally, it was found that the addition of triethylamine and trichloroacetic acid in the mobile phases significantly improved the enantioseparation for these two chiral stationary phases.

  • articleNo Access

    A FULLY ADDITIVE POLYMERIC PROCESS FOR THE FABRICATION AND ASSEMBLY OF SUBSTRATE AND COMPONENT LEVEL PACKAGING

    As the portable electronics industry continually drives electronic assemblies to higher functionality in smaller form factors, material compatibility and thermal dissipation issues are becoming considerably more acute. Most of the current approaches attempt to marry conventional materials technologies in order to achieve as much leverage as possible out of the established infrastructure. However, concurrent engineering of reliable, high-density electronic assemblies will require the introduction of a new material technology.

    A novel base technology that is applicable to all of the major packaging and redistribution elements in an electronic module is presented. A single family of polymer/metal composite conductors can be used for chip packaging redistribution layers, multichip module or multilayer PWB interconnects, and SMT assembly. High-density multilayer circuits with landless blind and buried vias can be fabricated by filling the conductor paste into photoimaged dielectrics and thermal processing. Via layers are prepared directly on the inherently planarized circuit layer in an identical fashion. Building up layers sequentially in this manner results in multilayer circuits built on a single substrate layer and minimizes the number of interfaces between dissimilar materials. Because these composite materials are applied in an additive fabrication method, metal substrates can be employed for high thermal dissipation and excellent CTE control over a wide temperature range. Two variants of the composite conductor can successfully replace solder for surface mount and chip on board assembly. These reliable, highly-thermally and electrically conductive materials are compatible with the standard metal finishes of conventional technologies and can be adopted piecemeal as desired; however, the largest reliability and cost benefit is realized when all of the elements are used in conjunction with one another.

    The conductor materials are based on interpenetrating polymer and metal networks that are formed in situ from metal particles and a thermosetting flux/binder. The metal network is formed when the alloy particles melt and react with adjacent high-melting point metal particles. Interaction also occurs between the alloy particles and pad, lead or previous trace metallizations provided they are solderable by alloys of tin. The new alloy composition created by the interdiffusion process within the bulk material has a higher melting point than the original alloy and thus solidifies immediately upon formation. This metallurgical reaction, known as transient liquid phase sintering, is facilitated by the polymer mixture. Integration of the polymer and metal networks is maintained by utilizing a thermosetting polymer system that cures simultaneously with the metallurgical reaction. Although similar in concept and performance to cermet inks, these compositions differ in that their process temperatures are compatible with conventional printed wiring board materials and that the polymeric binder remains to provide adhesion and fatigue resistance to the metallurgical network.

  • articleFree Access

    INFLUENCE OF CaF2–4LiF ADDITIVE ON SINTERING AND ENERGY STORAGE PERFORMANCE OF SrTiO3 CERAMICS

    The CaF2–4LiF additive was added into SrTiO3 ceramics in order to decrease the sintering temperature for compact pulse power application. The crystalline structure, microstructure and energy storage performance of sintered ceramics were studied. Incorporating CaF2–4LiF additive to SrTiO3 ceramics contributes to a notably enhancement of the energy storage density. The great enhancement in energy storage density occurred due to the notable increase in breakdown strength and the refinement of microstructure. With 2 at% additive, the samples exhibited an average breakdown strength of 31.8 kV/mm, and an energy storage density of 1.212 J/cm3 which is about 1.4 times higher than pure SrTiO3.

  • articleOpen Access

    The Comparison between Boron Carbide (B4C) with other Common Inhibitors on Physical and Mechanical Properties of WC/Co

    The hardness, toughness and sum of cracks measurement of fine-grained WC-Co hard metals were studied. Thirty commercial and experimental hard metal grades with different additives such as boron carbide (B4C), vanadium carbide (VC), chromium carbide (Cr3C2) and silicon carbide (SiC) were prepared in a commercial sinter HIP furnace. Physical, mechanical and microstructure properties were investigated to build up a representative hardness/sum of cracks measurement band. This band was then used to estimate the most effective sintering temperature and the amount of each additives. Afterwards, influence of grain growth inhibitors in optimum condition were compared. The results showed that the grades, doped with B4C and VC as growth inhibitor exhibits more hardness than other comparable doped alloys. However, Cr3C2 is favorable in toughness improvement.