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In order to study influence of automobile traffic on a local urban atmospheric environment, we have investigated suspended particulate matter (SPM) collected at sampling sites in a region which includes a major highway and a residential area in the southern part of Tokyo during August - November 1999. The atomic composition of each sample was measured by means of PIXE analysis using a 2.0 MeV proton beam. Sixteen elements were quantitatively measured. The positional dependence of SPM loading was determined for each element using samples simultaneously collected at three different sites. For the experimental results obtained for downwind conditions, the measured concentration as a function of the distance from the highway was compared with a simple calculation based on the Gaussian plume model. The concentration distribution of some heavy elements in the fine fraction is well reproduced by this analysis. It has been found that for ordinary moderate downwind conditions the area within 300-400 m from the highway is directly affected by emission due to the automobile traffic.
In order to study the influence of motor vehicles on a local soil environment, depth profiles of elemental concentration of urban roadside soil were investigated by means of thick-target PIXE analysis. For comparison, we analyzed the soil sampled in a university campus with very low traffic intensity. From the measured depth profiles, it was found that the roadside surface layers up to the depth of approximately 5 cm from the ground level are highly polluted by S and Zn. According to cluster analysis this pollution can be attributed to the deposition of tire dust due to the heavy vehicular traffic volumes on the highways.