In this paper, the non-leptonic three-body decays B→K∗(892)KπB→K∗(892)Kπ, ππππ, KKKK are studied by introducing two-meson distribution amplitude for the KπKπ, ππππ and KKKK pairs in naive and QCD factorization (QCDF) approaches, such that the analysis is simplified into quasi-two body decays. By considering that the vector meson is being ejected in factorization, the resonant and non-resonant contributions are analyzed by using intermediate mesons in Breit–Wigner resonance formalism and the heavy meson chiral perturbation theory (HMChPT), respectively. The calculated values of the resonant and non-resonant branching ratio of B→K∗(892)ππB→K∗(892)ππ, B→K∗(892)KπB→K∗(892)Kπ and B→K∗(892)KKB→K∗(892)KK decay modes are compared with the experimental data. For B→K0∗(892)π+π−B→K0∗(892)π+π− and B→K0∗(892)K+K−B→K0∗(892)K+K−, the non-resonant contributions are about 70–80% of experimental data, for which the total results by considering resonant contributions are in good agreement with the experiment.