The projected shell model (PSM) with the deformed single-particle states, generated by the standard Nilsson potential, is applied to study the negative-parity high spin states of 115–125Sb115–125Sb nuclei. The nuclear structure quantities like band structure and back-bending in moment of inertia have been calculated with PSM method and are compared with the available experimental data. In addition, the reduced transition probabilities, i.e., B(E2)(E2) and B(M1)(M1), are also obtained for the yrast band of these isotopes for the first time by using PSM wave function. A multi-quasiparticle structure has been predicted for 115–125Sb115–125Sb isotopes by the present PSM calculations.