Core–shell structure Fe@TiO2Fe@TiO2 was synthesized by sol–gel method. The photocatalytic degradation of methylene blue over the Fe@TiO2Fe@TiO2 reached 98% under UV light irradiation within 5 h. The band gap of the core–shell Fe@TiO2Fe@TiO2 was found to have a redshift through a sintering treatment. The redshifted Fe@TiO2Fe@TiO2 had a good performance of methylene-blue degradation (reaching 85%) under visible light irradiation for 5 h.