Effects of copper surface roughness RaRa on the properties of Ni–Co–Fe alloy coatings were studied by the measurement of coating roughness, thickness, hardness, substrate/coating bonding force and the potentiodynamic polarization curve. Results showed that at the current density of 4A/dm2, the coating roughness increased with the increase of the value of substrate RaRa in the range 0.1–1.1μμm. The coating thickness and hardness increased with the decrease of substrate RaRa. When substrate RaRa was 0.4μμm, the substrate/coating bonding force reached the maximum level. When substrate RaRa was 0.1μμm, the coating exhibited the best corrosion resistance. The comprehensive properties of the Ni–Co–Fe coatings can be effectively improved by controlling the surface roughness of copper substrate properly.