Let G be a noncompact connected simple Lie group, and (G,GΓ) a Klein four-symmetric pair. In this paper, we show a necessary condition for the discrete decomposability of unitarizable simple (𝔤,K)-modules for Klein for symmetric pairs. Precisely, if certain conditions hold for (G,GΓ), there does not exist a unitarizable simple (𝔤,K)-module that is discretely decomposable as a (𝔤Γ,KΓ)-module. As an application, for G=E6(−14), we obtain a complete classification of Klein four symmetric pairs (G,GΓ), with GΓ noncompact, such that there exists at least one nontrivial unitarizable simple (𝔤,K)-module that is discretely decomposable as a (𝔤Γ,KΓ)-module and is also discretely decomposable as a (𝔤σ,Kσ)-module for some nonidentity element σ∈Γ.