We employ the relativistic mean-field plus BCS (RMF+BCS) approach to study the behavior of sdsd-shell by investigating in detail the single particle energies, and proton and neutron density profiles along with the deformations and radii of even–even nuclei. Emergence of new shell closure, weakly bound structure and most recent phenomenon of bubble structure are reported in the sdsd-shell. 2222C, 2424O and 2626S are found to have a weakly bound structure due to particle occupancy in 2s1/2s1/2 state. On the other hand 2222O, 3434Ca and 34,4834,48Si are found with depleted central density due to the unoccupied 2s1/2s1/2 state and hence they are the potential candidates of bubble structure. 2222C and 2424O emerge as doubly magic with N=16N=16 in accord with the recent experiments and 2626S emerges as a new proton magic nucleus with Z=16Z=16. N=14N=14 and Z=14Z=14 are predicted as magic numbers in doubly magic 2222O, 3434Ca and 34,4834,48Si, respectively. These results are found in agreement with the recent experiments and have consistent with the other parameters of RMF and other theories.