Narrow Results

The drilling of film cooling holes on gas turbine blades made out of ceramic-coated superalloy improves the efficiency of the gas turbine and prolongs the life of the turbine blade. The purpose of this study was to investigate the effects of different stand-off distances (SODs) on abrasive water jet (AWJ)-pierced holes, in which the machining time, entry and exit hole diameters, overcut, hole taper, and surface morphology were studied. In this study, the water jet pressure (WJP) of 275MPa, piercing angle of $90^{\circ }$, dwell time of 0.2s, and abrasive flow rates (AFRs) of 350g/min and 400g/min were considered for the AWJ piercing operations. The entry and exit hole diameters and overcut linearly increased with an increase of SOD with different abrasive flow rates. And hole taper was observed at the coating and substrate sections in which it decreased with an increase of SOD up to 2mm, and a further increase of SOD increased the hole taper. Besides, the drilled holes were found to have an absence of delamination, cracks, and thermal defects. It was also noted that there is a transformation from a brittle to a ductile mode of erosion that may occur in the high-erosion kinetic energy impact region in the YSZ material section. Based on the experimental results, it is confirmed that SOD of 2mm became an influencing factor in AWJ for piercing quality holes in the YSZ-coated superalloy.

We have previously described the enhancement of piezoelectricity in low crystallinity Bi${}_{12}$TiO${}_{20}$–BaTiO₃ (BTO-BT) nanocomposites. This poses a question regarding the effect of the crystallinity on piezoelectricity. Here, the variation of crystallinity and structure that was developed along the temperature gradient was confirmed. The magnitude of the piezoelectric constant was found to have great relationship with the crystallinity and distortion of BiO₅ polyhedra of amorphous Bi${}_{12}$TiO${}_{20}$. The highest piezoelectric constant of 13pC/N was obtained together with the lowest crystallinity and highest degree of distortion of BiO₅ polyhedra. These results highlight the key role of the amorphous phase and further confirm the importance of distortion of BiO₅ polyhedra in influencing the piezoelectricity. In this view, one may also expect that macroscopic polarity could be improved by increasing the amorphous content and the degree distortion of the BiO₅ bonding units in the system.

Lead–free Sr${}_{1-x}$Ca_xTiO₃ ($x=0,0.4$) ceramics were synthesized via a solid state reaction technique at room temperature. The effects of ionic substitutions in A-sites between strontium and calcium on the structural and dielectric properties were investigated. XRD technique was used to identify the crystal structure and to demonstrate the phase purity. SEM observations have shown homogeneous morphologies for all samples. Dielectric measurements were investigated for a wide range of frequency (100Hz–1GHz) and temperature (25${}^{\circ }$C–250${}^{\circ }$C). Strontium substitution by calcium has not only led to a decrease in the dielectric permittivity value, but also to the loss tangent value by a considerable factor. Interesting values of the quality factor and the quite constant value ${\epsilon }^{\prime }\sim 200$ in extended frequency and temperature ranges show that SCT ceramic could be a real candidate for the development of monolithic ceramic capacitors dedicated to high-frequency lead-free components and/or to extremely high-temperature environments.

Ultrafine powder of CaCu_2.80Zn_0.20Ti₄O₁₂ ceramic was prepared using a novel semi-wet method. DTA/TG analysis of dry powder gives pre-information about formation of final product around 800°C. The formation of single phase was confirmed by X-ray diffraction analysis. The average particle size of sintered powder of the ceramic obtained from XRD and Transmission electron microscopy was found 59 nm and 102 nm, respectively. Energy Dispersive X-ray studies confirm the stoichiometry of the synthesized ceramic. Dielectric constant of the ceramic was found to be 2617 at room temperature at 1 kHz.

CaCu₃Ti₄O₁₂ (CCTO) ceramics which has perovskite structure gained considerable attention due to its giant permittivity. But it has high tan δ (0.1 at 1 kHz) at room temperature, which needs to be minimized to the level of practical applications. Hence, TeO₂ which is a good glass former has been deliberately added to CCTO nanoceramic (derived from the oxalate precursor route) to explore the possibility of reducing the dielectric loss while maintaining the high permittivity. The structural, morphological and dielectric properties of the pure CCTO and TeO₂ added ceramics were studied using X-ray diffraction, Scanning Electron Microscope along with Energy Dispersive X-ray Analysis (EDX), spectroscopy and Impedance analyzer. For the 2.0 wt.% TeO₂ added ceramics, there is a remarkable difference in the microstructural features as compared to that of pure CCTO ceramics. This sample exhibited permittivity values as high as 7387 at 10 KHz and low dielectric loss value of 0.037 at 10 kHz, which can be exploited for the high frequency capacitors application.

Yttrium Copper Titanate (Y_2/3Cu₃Ti₄O₁₂) nanoceramic is structurally analogous to CaCu₃Ti₄O₁₂ (CCTO). X-ray diffraction (XRD) of Y_2/3Cu₃Ti₄O₁₂ (YCTO) shows the presence of all normal peaks of CCTO. SEM micrograph exhibits the presence of bimodal grains of size ranging from 1–2 μm. Bright field TEM image clearly displays nanocrystalline particle which is supported by presence of a few clear rings in the corresponding selected area electron diffraction (SAED) pattern. It exhibits a high value of dielectric constant (ε′ = 8434) at room temperature and 100 Hz frequency with characteristic relaxation peaks. Impedance and modulus studies revealed the presence of temperature-dependent Maxwell–Wagner type of relaxation in the ceramic.

The desirable characteristics of Ba_6-3xNd_8+2xTi₁₈O₅₄ include high dielectric constant, low loss tangent, and high quality factor developed a new field for electronic applications. The microwave dielectric properties of Ba_6-3xNd_8+2xTi₁₈O₅₄, with x = 0.15 ceramics at different sintering temperatures (600–1300°C) were investigated. The phenomenon of polarization produced by the applied electric field was studied. The dielectric properties with respect to frequency from 1 MHz to 1.5 GHz were measured using Impedance Analyzer, and the results were compared and analyzed. The highest dielectric permittivity and lowest loss factor were defined among the samples. The complex dielectric modulus was evaluated from the measured parameters of dielectric measurement in the same frequency range, and used to differentiate the contribution of grain and grain boundary.

The polycrystalline ceramic Pb${}_{0.5}$Ba${}_{1.5}$BiVO₆ manifesting the complex double perovskite structure was tailored by the conventional solid state route at a moderate temperature. Qualitative phase analysis and formation of the ceramic were affirmed by XRD analysis. The X-ray powder diffraction pattern of the compound explored at room temperature affirms the single phase formation with double perovskite structure exhibiting rhombohedral phase. Microstructural analysis of the studied compound procured from the Scanning Electron Microscope (SEM) validates the formation of dense microstructures and nonuniformly distributed grains with minimal voids. Compositional analysis was shaped through the Electron Diffraction Spectroscopy (EDS) confirming the absence of contamination of any other metals apart from the mentioned ones. Dielectric (Cr and $tan\delta$) parameters of the compound were studied using the LCR analyzer at different temperatures and wide range of frequencies. The polarization and dielectric study affirms the presence of ferroelectricity in the material with transition temperature much above the room temperature. The tangent dielectric loss of this sample being almost minimal at room temperature attributes it to find applications in different grounds of electronics. Optical equities of the ceramic were further analyzed by the RAMAN, FTIR, UV–Vis and Photoluminescence spectroscopy.

The paper presents the results of a study of the microwave absorption properties of ceramic materials based on bismuth ferrite containing rare earth elements, as well as systems of solid solutions ($1-x$)BiFeO₃–xPbFe${}_{1/2}$Nb${}_{1/2}$O₃ in a wide range of component concentrations. The methodology for measuring and calculating the parameters of samples of the materials under study is described. The influence of structural and microstructural factors on the average and maximum level of microwave absorption of the materials under study in a wide frequency range is analyzed. A comparison of the microwave absorbing properties of these materials with industrial absorbers has been carried out, and prospects for application in microwave technology have been shown.