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In this paper, we prove the commutativity of the square in the chain level of both Chevalley Eilenberg complex of Lie homology and Hochschild complex, where the antisymmetrization map is used between the complexes. Originally, Loday proved this isomorphism by constructing a certain map satisfying relations of a presimplicial homotopy to prove the commutativity of the square mentioned above. Here, we present a different approach for the proof of the commutativity without constructing that certain map satisfying the relations of the presimplicial homotopy.