Please login to be able to save your searches and receive alerts for new content matching your search criteria.
In this study, the effect of Zn doping on photoluminescence, Chromaticity and structural properties of Y2O3:Eu compound were studied. For this purpose, various Y2O3:Eu samples containing different Zn2+ concentration and distribution were prepared by combustion method. The resultant samples were characterized by X-ray diffractometry (XRD), Photoluminescence spectroscopy (PL) and scanning electron microscopy (SEM). The XRD patterns of samples were also examined by Rietveld refinement method and results showed that the samples had nano-sized crystallites. It has been also shown that doping of Zn2+ ion in structure of Y2O3:Eu compound can effectively enhance the PL intensity and chromaticity of Y2O3:Eu compound, while doping of Zn at surface of Y2O3:Eu powder reduces PL intensity, crystallinity and chromaticity of this compound.
Nano ceramic Diopside (CaMgSi2O6) powders are synthesized by Solution Combustion Process(SCS) using Calcium nitrate, Magnesium nitrate as oxidizer and glycine as fuel, fumed silica as silica source. Ammonium nitrate (AN) is used as extra oxidizer. Effect of AN on Diopside phase formation is investigated. The adiabatic flame temperatures are calculated theoretically for varying amount of AN according to thermodynamic concept and correlated with the observed flame temperatures. A “Multi channel thermocouple setup connected to computer interfaced Keithley multi voltmeter 2700” is used to monitor the thermal events during the process. An interpretation based on maximum combustion temperature and the amount of gases produced during reaction for various AN compositions has been proposed for the nature of combustion and its correlation with the characteristics of as synthesized powder. These powders are characterized by XRD, SEM showing that the powders are composed of polycrystalline oxides with crystallite size of 58nm to 74nm.
A 3-dimensional computational fluid dynamics modeling is conducted on a direct injection diesel engine fueled by biodiesel using multi-dimensional software KIVA4 coupled with CHEMKIN. To accurately predict the oxidation of saturated and unsaturated agents of the biodiesel fuel, a multicomponent advanced combustion model consisting of 69 species and 204 reactions combined with detailed oxidation pathways of methyl decenoate (C11H22O2), methyl-9-decenoate (C11H20O2) and n-heptane (C7H16) is employed in this work. In order to better represent the real fuel properties, the detailed chemical and thermo-physical properties of biodiesel such as vapor pressure, latent heat of vaporization, liquid viscosity and surface tension were calculated and compiled into the KIVA4 fuel library. The nitrogen monoxide (NO) and carbon monoxide (CO) formation mechanisms were also embedded. After validating the numerical simulation model by comparing the in-cylinder pressure and heat release rate curves with experimental results, further studies have been carried out to investigate the effect of combustion chamber design on flow field, subsequently on the combustion process and performance of diesel engine fueled by biodiesel. Research has also been done to investigate the impact of fuel injector location on the performance and emissions formation of diesel engine.
We have studied the phase transition from hadronic to quark matter inside neutron stars, we calculate the rate and emissivity for all the relevant weak interaction processes and solve the Boltzmann transport equation, considering the effect of strong interactions in the perturbative regime to the order of QCD coupling constant αc. We find that the neutrino and antineutrino emissivity is around of 1053 erg.