We have studied the compression (P) wave band structures at a low frequency in two-dimensional solid–solid phononic crystals. The plane-wave expansion method based on the decomposition of elastic waves was used. The pressure field distribution of P-wave localized modes at Γ points in the lowest bands, including multiple flat bands of systems comprising different configurations, were analyzed. The results show that a lower symmetry of the scatterer are an effective method to enhance the localization of vibration modes. The property has potential applications in the design of waveguides.