In this chapter we study the relationships among random variables, which will be characterized by the joint probability distribution of random variables. Most insights into multivariate distributions can be gained by focusing on bivariate distributions. We first introduce the joint probability distribution of a bivariate random vector (X, Y ) via the characterization of the joint cumulative distribution function, the joint probability mass function (when (X, Y ) are discrete), and the joint probability density function (when (X, Y ) are continuous) respectively. We then characterize various aspects of the relationship between X and Y using the conditional distributions, correlation, and conditional expectations. The concept of independence and its implications on the joint distributions, conditional distributions and correlation are also discussed. We also introduce a class of bivariate normal distributions.