Strontium hexaferrite powder synthesised conventionally has been treated in nitrogen atmosphere and subsequently calcined in air (Nitrogen Treatment and Re-calcination : NTR Process). The phase identification studies by means of X-ray diffraction (XRD) showed decomposition of strontium hexaferrite and reduction of the resultant iron oxide (Fe2O3) during the reaction with nitrogen. According to high resolution scanning electron microscopy (HRSEM) studies, reduction during nitrogenation, resulted in the division of some big grains into much finer sub-grains, strontium hexaferrite, Fe3O4 and Sr7Fe10O22 were the main phases obtained after reduction. The hexaferrite phase reformed on subsequent calcination. The magnetic measurements indicated a significant decrease in the intrinsic coercivity during nitrogenation due to the formation of Fe3O4. However, after a re-calcination process, the remanence and maximum magnetisation (i.e. magnetisation at 1100 kA/m ) exhibited values close to the initial values before treatment but the value of the intrinsic coercivity was higher than that prior to nitrogenation. The microstructure showed that this could be attributed to very fine grains which originated from the fine sub-grains formed during nitrogenation.
The selected temperature was 950°C for nitrogenation and 1000°C for re-calcination. The time and initial pressure were selected to be 5 hours and 1 bar respectively. The highest coercivity obtained after re-calcination was 340 kA/m.